Conformation of diethylglyoxime in uranyl complexes
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- 作者：A. G. Beirakhov ; I. M. Orlova ; A. V. Rotov…
- 刊名：Russian Journal of Inorganic Chemistry
- 出版年：2016
- 出版时间：December 2016
- 年：2016
- 卷：61
- 期：12
- 页码：1522-1529
- 全文大小：
- 刊物类别：Chemistry and Materials Science
- 刊物主题：Inorganic Chemistry;
- 出版者：Pleiades Publishing
- ISSN：1531-8613
- 卷排序：61
文摘
New complexes of uranyl with diethylglyoxime have been synthesized and studied. A feature of these complexes is the tetradentate bridging coordination of the ligand in both cis- and trans-conformations. The structure of organic ligand C6H12N2O2 and binuclear complex (CN3H6)4[(UO2)2(C6H10N2O2)(CO3)(C2O4)2] ∙ H2O have been determined by X-ray diffraction.