Coordination compounds of CuCl₂ with 1-(N-heterylmethyl)silatranes

详细信息    查看全文

• 作者：Yu. I. Bolgova ; E. F. Belogolova ; V. V. Belyaeva…
• 关键词：coordination compounds ; 1 ; (N ; pyrrolylmethyl)silatrane ; 1 ; (N ; indolylmethyl)silatrane ; 1 ; (N ; carbazolylmethyl)silatrane ; copper(II) chloride ; quantum chemical calculations
• 刊名：Russian Chemical Bulletin
• 出版年：2016
• 出版时间：April 2016
• 年：2016
• 卷：65
• 期：4
• 页码：1039-1046
• 全文大小：
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry/Food Science, general; Organic Chemistry; Inorganic Chemistry;
• 出版者：Springer US
• ISSN：1573-9171
• 卷排序：65

文摘

Reactions of CuCl₂ with 1-(N-indolylmethyl)and 1-(N-carbazolylmethyl)silatranes (L) afforded new complexes CuCl2•L. Quantum chemical calculations of these complexes and a CuII complex with 1-(N-pyrrolylmethyl)silatrane showed that the Cu atom is coordinated to both the equatorial O atom of the silatranyl group and the π-system of the ligandś heterocycle.