Inhibition of Zinc Corrosion by Some Benzaldehyde Derivatives in HCl Solution

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• 作者：M. Abdallah (13) metwally555@yahoo.com
  I. Zaafarany (1)
  A. S. Fouda (2) asfouda@mans.edu.eg
  D. Abd El-Kader (2)
• 关键词：benzaldehyde derivatives &#8211 ; corrosion inhibitors &#8211 ; HCl &#8211 ; synergistic effect &#8211 ; zinc
• 刊名：Journal of Materials Engineering and Performance
• 出版年：2012
• 出版时间：June 2012
• 年：2012
• 卷：21
• 期：6
• 页码：995-1002
• 全文大小：611.4 KB
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• 作者单位：1. Department of Chemistry, Faculty of Applied Science, Umm Al-Qura University, Makkah Al Mukaramha, Saudi Arabia2. Department of Chemistry, Faculty of Science, El-Mansoura University, El Mansoura, 35516 Egypt3. Department of Chemistry, Faculty of Science, Benha University, Benha, Egypt
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Characterization and Evaluation Materials
  Materials Science
  Tribology, Corrosion and Coatings
  Quality Control, Reliability, Safety and Risk
  Engineering Design
  
• 出版者：Springer US
• ISSN：1544-1024

文摘

The effect of some benzaldehyde derivatives on the corrosion of zinc in 0.5 M HCl solution is studied in this article using mass loss, potentiodynamic polarization, and electrochemical impedance spectroscopy (EIS) techniques. The percentage inhibition efficiency (%In) was found to increase with increasing concentration of the inhibitor and with decreasing temperature. Polarization studies indicated that all of the compounds studied are mixed-type inhibitors. The inhibitive action of these benzaldehyde derivatives has been discussed in view of the adsorption on the zinc surface. The adsorption process follows Temkin’s isotherm. The addition of KSCN, KI, and KBr to benzaldehyde derivatives has enhanced the inhibition efficiency because of synergistic effect. The mechanism of inhibition process is discussed in the light of the chemical structures of the investigated inhibitors.