Measuring the thermodynamic properties of saturated solid solutions in the Ag2Te-Bi-Bi2Te3 system by the electromotive force method

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• 作者：M. V. Prokhorenko ; M. V. Moroz ; P. Yu. Demchenko
• 关键词：Ag2Te ; Bi ; Bi2Te3 system ; inorganic compounds ; thermodynamic functions ; electromotive force method
• 刊名：Russian Journal of Physical Chemistry A, Focus on Chemistry
• 出版年：2015
• 出版时间：August 2015
• 年：2015
• 卷：89
• 期：8
• 页码：1330-1334
• 全文大小：309 KB
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• 作者单位：M. V. Prokhorenko (1)
  M. V. Moroz (2)
  P. Yu. Demchenko (3)
  
  1. Lviv Polytechnic National University, Lviv, 79013, Ukraine
  2. National University of Water Management and Nature Resources Use, Rivne, 33028, Ukraine
  3. Ivan Franko National University of Lviv, Lviv, 79000, Ukraine
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Physical Chemistry
  Russian Library of Science
  
• 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
• ISSN：1531-863X

文摘

The temperature dependence of the electromotive force (EMF) of Ag|AgI|glass Ag2GeS3|D galvanic elements (where Ag, D are galvanic element electrodes, D is equilibrium three-phase alloys in the Ag2Te-Bi-Bi2Te3 system, AgI|glass Ag2GeS3 is a two-layer membrane with purely ionic (Ag+) conductivity) is studied in the range of 490-50 K. Analytical equations are obtained for the temperature dependences of the Gibbs energies of the formation of saturated solid solutions of the Bi14Te6, Bi2Te, BiTe, and Bi2Te phases from elements in the Ag2Te-Bi-Bi2Te3 system. E(T) analytical equations are used to calculate the standardstate thermodynamic functions of saturated solid solutions of the Bi14Te6, Bi2Te, BiTe, and Bi2Te3 phases in the Ag2Te-Bi-Bi2Te3 system.