Modeling the biosorption of basic dyes from binary mixtures

详细信息    查看全文

• 作者：M. E. Fernandez (1)
  P. R. Bonelli (1)
  A. L. Cukierman (1)
  N. O. Lemcoff (2)
  
  1. Programa de Investigaci贸n y Desarrollo de Fuentes Alternativas de Materias Primas y Energ铆a-PINMATE ; Departamento de Industrias ; Facultad de Ciencias Exactas y Naturales ; Universidad de Buenos Aires ; Ciudad Universitaria ; Buenos Aires ; Argentina
  2. Department of Engineering and Science ; Rensselaer Polytechnic Institute Hartford ; 275 Windsor Street ; Hartford ; CT ; 06120 ; USA
  
• 关键词：Biosorption ; Basic dyes ; Dynamic studies ; Modeling
• 刊名：Adsorption
• 出版年：2015
• 出版时间：April 2015
• 年：2015
• 卷：21
• 期：3
• 页码：177-183
• 全文大小：1,493 KB
• 参考文献：1. COMSOL: COMSOL Multiphysics, multipurpose software platform, http://www.comsol.com/comsol-multiphysics (2015). Accessed 12 Jan 2015
  2. Crini, G, Badot, P-M (2008) Application of chitosan, a natural aminopolysaccharide, for dye removal from aqueous solutions by adsorption processes using batch studies: A review of recent literature. Prog. Polym. Sci. 33: pp. 399-447 CrossRef
  3. Dogan, M, Abak, H, Alkan, M (2009) Adsorption of methylene blue onto hazelnut shell: Kinetics, mechanism and activation parameters. J. Hazard. Mater. 164: pp. 172-181 CrossRef
  4. Eftekari, S, Habibi-Yankgjeh, A, Sohrabnezhad, Sh (2010) Application of AIMCM-41 for competitive adsorption of methylene blue and rhodamine B: Thermodynamic and kinetic studies. J. Hazard. Mater. 178: pp. 349-355 CrossRef
  5. Fernandez, ME, Nunell, GV, Bonelli, PR, Cukierman, AL (2010) Effectiveness of Cupressus sempervirens cones as biosorbent for the removal of basic dyes from aqueous solutions in batch and dynamic modes. Bioresour. Technol. 101: pp. 9500-9507 CrossRef
  6. Fernandez, ME, Nunell, GV, Bonelli, PR, Cukierman, AL (2012) Batch and dynamic biosorption of basic dyes from binary solutions by alkaline-treated cypress cone chips. Bioresour. Technol. 106: pp. 55-62 CrossRef
  7. Ghaedi, M, Hajati, S, Barazesh, B, Karimi, F, Ghezelbash, G (2013) Saccharomyces cerevisiae for the biosorption of basic dyes from binary component systems and high order derivative spectrophotometric method for simultaneous analysis of Brilliant green and Methylene blue. J. Ind. Eng. Chem. 19: pp. 227-233 CrossRef
  8. Gunn, DJ (1987) Axial and radial dispersion in fixed beds. Chem. Eng. Sci. 42: pp. 363-373 CrossRef
  9. Gupta, VK, Suhas, (2009) Application of low-cost adsorbents for dye removal 鈥?A review. J. Environ. Manage. 90: pp. 2313-2342 CrossRef
  10. Ho, YS, McKay, G (1999) Pseudo-second order model for sorption processes. Process Biochem. 34: pp. 451-465 CrossRef
  11. Jafari-zare, F, Habibi-yangjeh, A (2010) Competitive Adsorption of Methylene Blue and Rhodamine B on Natural Zeolite: Thermodynamic and Kinetic Studies. Chin. J. Chem. 28: pp. 349-356 CrossRef
  12. McKay, G, Al Duri, B (1987) Simplified model for the equilibrium adsorption of dyes from mixtures using activated carbon. Chem. Eng. Process. 22: pp. 145-156 CrossRef
  13. Noroozi, B, Sorial, GA (2013) Applicable models for multi-component adsorption of dyes: A review. Journal of Environmental Sciences 25: pp. 419-429 CrossRef
  14. Ozcan, AS, Tetik, S, Ozcan, A (2004) Adsorption of acid dyes from aqueous solutions onto sepiolite. Sep. Sci. Technol. 39: pp. 301-320 CrossRef
  15. Pereira, L, Alves, M Dyes 鈥?Environmental impact and remediation. In: Malik, A, Grohmann, E eds. (2012) Environmental protection strategies for sustainable development. Springer, Netherlands, pp. 111-154 CrossRef
  16. Qiu, H, Pan, BC, Zhang, QJ, Zhang, WM, Zhang, QX (2009) Critical review in adsorption kinetic models. J. Zhejiang Univ. Science A 10: pp. 716-724 CrossRef
  17. Ruthven, DM (1984) Principles of Adsorption and Adsorption Processes. John Wiley, New York
  18. Ruthven, DM, Farooq, S, Knaebel, KS (1994) Pressure Swing Adsorption. VCH Publishers, New York
  19. Sheindorf, Ch, Rebhun, M, Sheintuch, M (1981) A Freundlich-type multicomponent isotherm. J. Colloid Interface Sci. 79: pp. 136-142 CrossRef
  20. Sheindorf, C, Rebhun, M, Sheintuch, M (1982) Organic pollutants adsorption from multicomponent systems modeled by Freundlich type isotherm. Water Res. 16: pp. 357-362 CrossRef
  21. Turabik, M (2008) Adsorption of basic dyes from single and binary component systems onto bentonite: simultaneous analysis of basic red 46 and basic yellow 28 by first order derivative spectrophotometric analysis method. J. Hazard. Mater. 158: pp. 52-64 CrossRef
  22. U.S. Environmental Protection Agency, Profile of the textile industry, Sector Notebook Project EPA/310-R-97-009, 1997
  23. Walker, GM, Weatherley, LR (2000) Prediction of bisolute dye adsorption isotherms on activated carbon. Trans. IChemE 78: pp. 219-223 CrossRef
  24. Xu, Z, Cai, JG, Pan, BC (2013) Mathematically modeling fixed-bed adsorption in aqueous systems. J. Zhejiang Univ. Science A 14: pp. 155-176 CrossRef
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Surfaces and Interfaces and Thin Films
  Industrial Chemistry and Chemical Engineering
  Engineering Thermodynamics and Transport Phenomena
  
• 出版者：Springer Netherlands
• ISSN：1572-8757

文摘

The biosorption of basic dyes, methylene blue and rhodamine B, from binary aqueous solutions onto cypress cone chips, was analyzed through mathematical modeling. This study aimed at introducing a novel model to predict the dynamic binary sorption of the dyes. It consisted of a modified Langmuir multicomponent isotherm coupled with a linear driving force model. Experimental data from recent studies using the untreated and alkaline-treated biosorbent was used to determine the model parameters, and the breakthrough predictions are in good agreement with the experimental results. Useful information on the effects of bed length and feed concentration on the breakthrough time and mass transfer length was obtained. This can guide the design and optimization of the biosorbent column.