Introduction of W-doped ZnO nanocomposite as a new and efficient nanocatalyst for the synthesis of biscoumarins in water

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• 作者：Farhad Shirini (1)
  Masoumeh Abedini (1)
  Solmaz Zamani (1)
  Hadi Fallah Moafi (1)
  
  1. Department of Chemistry ; College of Science ; University of Guilan ; P.O. Box 1914 ; 41335 ; Rasht ; Iran
  
• 关键词：Biscoumarins ; Aldehydes ; Protected aldehydes ; W ; doped ZnO nanocomposite ; Heterogeneous reaction conditions
• 刊名：Journal of Nanostructure in Chemistry
• 出版年：2015
• 出版时间：March 2015
• 年：2015
• 卷：5
• 期：1
• 页码：123-130
• 全文大小：569 KB
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• 刊物主题：Nanochemistry;
• 出版者：Springer Berlin Heidelberg
• ISSN：2193-8865

文摘

W-doped ZnO nanocomposite (W-ZnO) is easily prepared and characterized using a variety of techniques including XRD, TEM, BET, ICP-OES and SEM. This reagent can be used as an efficient and heterogeneous catalyst for the preparation of biscoumarins in water under mild conditions. Easy preparation of the catalyst, mild reaction conditions, easy work-up procedure, excellent yields and short reaction times are some of the advantages of this work. In addition, in this article and for the first time, the preparation of biscoumarins from the protected derivatives of aldehydes including oximes, hydrazones and 1,1-diacetates is reported.