Design, Synthesis and pH Sensing Properties of Novel PAMAM Light-Harvesting Dendrons Based on Rhodamine 6G and 1,8-naphthalimide
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- 作者：Nikolai I. Georgiev (1)
Vladimir B. Bojinov (1)
Alexandrina I. Venkova (1) - 关键词：1 ; 8 ; Naphthalimide ; Rhodamine 6G ; PAMAM dendrimers ; Fluorescence ; Light harvesting ; FRET ; pH sensing
- 刊名：Journal of Fluorescence
- 出版年：2013
- 出版时间：May 2013
- 年：2013
- 卷：23
- 期：3
- 页码：459-471
- 全文大小：936KB
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Vladimir B. Bojinov (1)
Alexandrina I. Venkova (1)
1. Department of Organic Synthesis, University of Chemical Technology and Metallurgy, 8 Kliment Ohridsky Bulv., 1756, Sofia, Bulgaria - ISSN：1573-4994
文摘
Herein we report on the design, divergent synthesis and photophysical behavior of novel PAMAM light-harvesting dendrons from first and second generation. The surface of novel compounds is labeled with 4-alkylamino-1,8-naphthalimide yellow-green emitting “donor-fluorophores capable of absorbing light and efficiently transferring the energy to a single rhodamine “acceptor-dye. Due to the pH dependent rhodamine absorption the novel systems show “off-on-switching energy transfer mechanism from alkaline to acid media. The results obtained illustrate the high potential of the synthesized wavelength-shifting fluorophores as efficient pH chemosensing materials.