Fluorescence measurements have been used to characterize the velocity of atoms in a femtosecond-laser-produced plasma. Nanogram amounts of a copper sample were ablated by the focused radiation (λ= 775 nm) of an all-solid-state laser. The laser was operated at a pulse rate of 10 Hz with an energy of 200 &mgr;J per pulse. The microplasma expanded into a defined argon atmosphere of pressures between 0.02 and 850 mbar. Atomic fluorescence was excited in the laser plume by a dye-laser pulse with the wavelength set to the line Cu I 282.4 nm. The narrowed beam of the dye-laser was directed into the plasma at different heights above the sample surface. The fluorescence radiation was measured with an échelle-spectrometer, equipped with an intensified-charge-coupled device as the detector. The velocity depends strongly on the pressure of the ambient atmosphere and the distance from the sample surface. The highest velocity found at an argon pressure of 0.02 mbar was 1.0×106 cm s-1.