Iα?→?Iβ transition of cellulose under ultrasonic radiation
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- 作者：Benjamin Briois (1)
Tsuguyuki Saito (2)
Christian Pétrier (3)
Jean-Luc Putaux (1)
Yoshiharu Nishiyama (1)
Laurent Heux (1)
Sonia Molina-Boisseau (1) - 关键词：Cellulose microfibrils ; Glaucocystis ; Low frequency sonication ; Allomorphic transition
- 刊名：Cellulose
- 出版年：2013
- 出版时间：April 2013
- 年：2013
- 卷：20
- 期：2
- 页码：597-603
- 全文大小：556KB
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Tsuguyuki Saito (2)
Christian Pétrier (3)
Jean-Luc Putaux (1)
Yoshiharu Nishiyama (1)
Laurent Heux (1)
Sonia Molina-Boisseau (1)
1. Centre de Recherches sur les Macromolécules Végétales (CERMAV-CNRS), (affiliated with Université Joseph Fourier (UJF)), BP 53, 38041, Grenoble Cedex 9, France
2. Department of Biomaterials Sciences, Graduate School of Agricultural and Life Sciences, The University of Tokyo, Tokyo, 113-8657, Japan
3. Laboratoire Rhéologie et Procédés, UMR 5520, BP 53, 38041, Grenoble Cedex 9, France - ISSN：1572-882X
文摘
Aqueous suspensions of dispersed Glaucocystis cellulose microfibrils were sonicated at 4?°C for 3?h, using 24?kHz ultrasonic waves. This treatment induced a variety of ultrastructural defects, as the microfibrils became not only shortened, but also presented substantial damage materialized by kinks and subfibrillation. Upon analysis by X-ray diffraction and 13C solid-state NMR spectroscopy, it was found that the initial sample that contained 90?% of cellulose Iα allomorph became, to a large extent, unexpectedly converted into the Iβ phase, while the loss of crystallinity was only moderate during the sonication treatment.