Study of the metal-exchange reaction between Cd(II) octa(4-bromophenyl)tetraazaporphyrinate and cobalt chloride in organic solvents

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• 作者：S. V. Zvezdina ; N. V. Chizhova…
• 关键词：metal ; exchange reaction ; Cd(II) octa(4 ; bromophenyl)tetraazaporphyrinate ; Co(III) octa(4 ; bromophenyl) tetraazaporphyrinate
• 刊名：Russian Journal of General Chemistry
• 出版年：2015
• 出版时间：April 2015
• 年：2015
• 卷：85
• 期：4
• 页码：911-914
• 全文大小：188 KB
• 参考文献：1. Porfiriny: spektroskopiya, elektrokhimiya, primenenie (Porphyrins: Spectroscopy, Electrochemistry, Application), N.S. Enikolopyan, N.S., Ed., Moscow: Nauka, 1987.
  2. Porphyrin Handbook, Smith, K., Kadish, K., and Guillard, R., Eds., New York: Academic, 2000, vol. 3, p. 129.
  3.Krestov, G.A. and Berezin, B.D., Osnovnye ponyatiya sovremennoy khimii (Fumdamentals of Modern Chemistry), Leningrad: Khimiya, 1986.
  4.Berezin, B.D., Zvezdina, S.V., and Berezin, M.B., Russ. J. Gen. Chem., 2013, vol. 83, no. 7, p. S. 1410. DOI: 10.1134/S1070363213070189.View Article
  5.Zvezdina, S.V., Mal鈥檛seva, O.V., Chizhova, N.V., and Mamardashvili, N.Zh., Abstracts of Papers, XXXI Nauchnaya sessiya Rossiiskogo seminara po khimii porfirinov i ikh analogov (XXXI Scientific Session of the Russian Seminar for the Chemistry of Porphyrins and Their Analogs), Ivanovo, 2014, p. 55.
  6.Drobysheva, A.N., Karmanova, L.P., and Berezin, B.D., Zh. Fiz. Khim., 1977, vol. 57, no. 6, p. 1344.
  7.Entelis, S.G. and Tiger, R.P., Kinetika reaktsii v zhidkoi faze (Kinetics of Liquid-Phase Reactions), Moscow: Khimiya, 1973.
  
• 作者单位：S. V. Zvezdina (1)
  N. V. Chizhova (1)
  N. Zh. Mamardashvili (1)
  
  1. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153045, Russia
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Chemistry
  Russian Library of Science
  
• 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
• ISSN：1608-3350

文摘

The metal-exchange reaction between Cd(II) octa(4-bromophenyl)tetraazaporphyrinate and cobalt chloride in dimethylformamide and dimethyl sulfoxide was studied by spectrophotometry. Kinetic parameters of the metal-exchange reaction were determined. A possible stoichiometric mechanism of the reaction was proposed. Cobalt(III) octa(4-bromophenyl)tetraazaporphyrinate was synthesized and characterized.