Preparation and visible-light photocatalytic performances of g-C3N4 surface hybridized with a small amount of CdS nanoparticles
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  • 作者:Desong Wang ; Zexuan Xu ; Qingzhi Luo ; Xueyan Li ; Jing An…
  • 刊名:Journal of Materials Science
  • 出版年:2016
  • 出版时间:January 2016
  • 年:2016
  • 卷:51
  • 期:2
  • 页码:893-902
  • 全文大小:2,479 KB
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  • 作者单位:Desong Wang (1)
    Zexuan Xu (1)
    Qingzhi Luo (1)
    Xueyan Li (1)
    Jing An (1)
    Rong Yin (1)
    Cai Bao (2)

    1. School of Sciences, Hebei University of Science and Technology, Shijiazhuang, 050018, China
    2. College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang, 050018, Hebei, China
  • 刊物类别:Chemistry and Materials Science
  • 刊物主题:Chemistry
    Materials Science
    Characterization and Evaluation Materials
    Polymer Sciences
    Continuum Mechanics and Mechanics of Materials
    Crystallography
    Mechanics
  • 出版者:Springer Netherlands
  • ISSN:1573-4803
文摘
An efficient visible-light photocatalyst was successfully synthesized by surface-hybridizing graphitic carbon nitride (g-C3N4) using a small amount of cadmium sulfide (CdS) nanoparticles. The CdS/g-C3N4 nanocomposites were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, Raman spectroscopy, scanning electron microscopy, transmission electron microscopy, UV鈥揤is diffuse reflectance spectroscopy, photoluminescence spectroscopy, electrochemical impedance spectroscopy, and photocurrent鈥搕ime measurement. The photocatalytic activity of the CdS/g-C3N4 nanocomposites was investigated by evaluating the degradation of Rhodamine B (RhB) under visible-light irradiation. The effects of the CdS content on the nanocomposites, initial RhB concentration, pH value of the investigated system, and dosage of CdS/g-C3N4 nanocomposites on the visible-light photocatalytic activity were systematically investigated. The results revealed that the visible-light photocatalytic activity of g-C3N4-based photocatalysts was significantly improved by surface-hybridization of a small amount of CdS nanoparticles, increased as both CdS content on the nanocomposites and dosage of CdS/g-C3N4 nanocomposites increased, while increased at first and then decreased as both initial RhB concentration and pH value of the investigated system increased. The visible-light photocatalytic mechanism of the CdS/g-C3N4 nanocomposites was discussed. Electronic supplementary materialThe online version of this article (doi:10.鈥?007/鈥媠10853-015-9417-y) contains supplementary material, which is available to authorized users.

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