Can Pearlite form Outside of the Hultgren Extrapolation of the Ae3 and Acm Phase Boundaries?

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• 作者：M. M. Aranda ; R. Rementeria ; C. Capdevila…
• 刊名：Metallurgical and Materials Transactions A
• 出版年：2016
• 出版时间：February 2016
• 年：2016
• 卷：47
• 期：2
• 页码：649-660
• 全文大小：2,892 KB
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• 作者单位：M. M. Aranda (1)
  R. Rementeria (1)
  C. Capdevila (1)
  R. E. Hackenberg (2)
  
  1. Materalia Research Group, Centro Nacional de Investigaciones Metalúrgicas (CENIM), Consejo Superior Investigaciones Científicas (CSIC), Madrid, Spain
  2. Materials Science and Technology Division, Los Alamos National Laboratory, Los Alamos, NM, USA
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Materials Science
  Metallic Materials
  Structural Materials
  Physical Chemistry
  Ceramics,Glass,Composites,Natural Materials
  
• 出版者：Springer Boston
• ISSN：1543-1940

文摘

It is usually assumed that ferrous pearlite can form only when the average austenite carbon concentration C ₀ lies between the extrapolated Ae3 (γ/α) and Acm (γ/θ) phase boundaries (the “Hultgren extrapolation”). This “mutual supersaturation” criterion for cooperative lamellar nucleation and growth is critically examined from a historical perspective and in light of recent experiments on coarse-grained hypoeutectoid steels which show pearlite formation outside the Hultgren extrapolation. This criterion, at least as interpreted in terms of the average austenite composition, is shown to be unnecessarily restrictive. The carbon fluxes evaluated from Brandt’s solution are sufficient to allow pearlite growth both inside and outside the Hultgren Extrapolation. As for the feasibility of the nucleation events leading to pearlite, the only criterion is that there are some local regions of austenite inside the Hultgren Extrapolation, even if the average austenite composition is outside.