Silicon-containing anodes with high capacity loading for lithium-ion batteries

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• 作者：S. P. Kuksenko (1)
  
• 关键词：hybrid electrodes for lithium ; ion batteries ; “nano ; Si/SiO2/hard carbon-ceramic frame ; ordered composite ; silicon nanopowder ; the MAG synthetic graphite ; capacity loading ; accumulated irreversible capacity
• 刊名：Russian Journal of Electrochemistry
• 出版年：2014
• 出版时间：June 2014
• 年：2014
• 卷：50
• 期：6
• 页码：537-547
• 全文大小：
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• 作者单位：S. P. Kuksenko (1)
  
  1. Chuiko Institute of Surface Chemistry, National Academy of Sciences of Ukraine, ul. Generala Naumova 17, Kiev, 03164, Ukraine
  
• ISSN：1608-3342

文摘

Comparative analysis of cycling performance of hybrid electrodes based on the MAG synthetic graphite mechanic mixtures with silicon nanopowder and “nano-Si/SiO2/hard carbon-ceramic frame-ordered composite in 1 M LiPF6 solution in a monofluoroethylene carbonate-ethyl methyl carbonate mixture (30: 70, v/v), added with 3 wt % vinylene carbonate and 2 wt % ethylene sulfite, is performed. The high capacity loading (up to 6.8 mA h cm? at the electrode layer thickness of 37 μm) and acceptable accumulated irreversible capacity of the composite-containing electrodes are achieved, due to the electrodes-high density and stable silicon-containing electrode/electrolyte interface formation.