Chemical transformations of tetracyclo[3.3.1.1.^3,7.0.^1,3]decane (1,3-dehydroadamantane): I. Reaction of 1,3-dehydroadamantane with carboxylic acids esters

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• 作者：V. M. Mokhov ; V. V. Burmistrov ; G. M. Butov
• 刊名：Russian Journal of Organic Chemistry
• 出版年：2016
• 出版时间：August 2016
• 年：2016
• 卷：52
• 期：8
• 页码：1118-1120
• 全文大小：232 KB
• 刊物主题：Organic Chemistry;
• 出版者：Springer US
• ISSN：1608-3393
• 卷排序：52

文摘

Adamantylation of carboxylic acids esters was performed with 1,3-dehydroadamantane for the first time. The reaction proceeds under mild conditions and can be used as a convenient single stage procedure for the synthesis of esters of branched carboxylic acids having an adamantyl group in the α-position to the carbonyl group.