Pyrolysis of 3-carene: Experiment, Theory and Modeling

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• 作者：N SHARATH ; H K CHAKRAVARTY ; K P J REDDY ; P K BARHAI…
• 关键词：Shock Tube ; Monoterpene ; Thermal Decomposition ; Isoprene
• 刊名：Journal of Chemical Sciences
• 出版年：2015
• 出版时间：December 2015
• 年：2015
• 卷：127
• 期：12
• 页码：2119-2135
• 全文大小：4,539 KB
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• 作者单位：N SHARATH (1)
  H K CHAKRAVARTY (2) (4)
  K P J REDDY (1)
  P K BARHAI (3)
  E ARUNAN (2)
  
  1. Department of Aerospace Engineering Indian Institute of Science, Bangalore, India
  2. Department of Inorganic and Physical chemistry, Indian Institute of Science, Bangalore, India
  4. Max Planck Institute for Chemistry, Mainz, Germany
  3. Department of Applied Physics, Birla Institute of Technology, Mesra, Ranchi, India
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Chemistry
  
• 出版者：Springer India
• ISSN：0973-7103

文摘

Thermal decomposition studies of 3-carene, a bio-fuel, have been carried out behind the reflected shock wave in a single pulse shock tube for temperature ranging from 920 K to 1220 K. The observed products in thermal decomposition of 3-carene are acetylene, allene, butadiene, isoprene, cyclopentadiene, hexatriene, benzene, toluene and p-xylene. The overall rate constant for 3-carene decomposition was found to be $$ \mathrm {k/s}^{-1}=10^{(9.95\,\pm \,0.54)}\; \exp (-40.88 \pm 2.71 \, \mathrm {kcal mol}^{\mathrm {-1}}/\text {RT}) . $$