Study towards diversity oriented synthesis of optically active substituted cyclopentane fused carbocyclic and oxacyclic medium-sized rings: Competition between Grubbs-II catalyzed ring closing olefin metathesis and ring closing carbonyl-olefin metathesis
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- 作者：P CHAKRABORTY ; S C ROY
- 关键词：Diversity ; oriented synthesis ; bicyclic frameworks ; ring closing metathesis ; Grubbs ; II catalyst ; carbonyl ; olefin metathesis.
- 刊名：Journal of Chemical Sciences
- 出版年：2016
- 出版时间：December 2016
- 年：2016
- 卷：128
- 期：12
- 页码：1831-1840
- 全文大小：
- 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry/Food Science, general;
- 出版者：Springer India
- ISSN：0973-7103
- 卷排序：128
文摘
A study towards diversity-oriented synthesis of optically active cyclopentane fused bicyclic frameworks has been accomplished. The common intermediate was prepared from commercially available starting material (S)-carvone. The observations on competition between Grubbs-II catalyzed ring closing metathesis (RCM) and ring closing carbonyl-olefin metathesis (RCCOM) were the key features of the study.