The kinetics of the reaction between cyclopentene and aqueous hydrogen peroxide under phase-transfer catalysis

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• 作者：A. E. Meshechkina ; L. V. Mel’nik ; G. V. Rybina ; S. S. Srednev…
• 关键词：cyclopentene ; hydrogen peroxide ; 1 ; 2 ; epoxycyclopentane ; 1 ; 2 ; cyclopentanediol ; phase ; transfer catalysis ; kinetics ; reaction rate ; mathematical model
• 刊名：Petroleum Chemistry
• 出版年：2015
• 出版时间：January 2015
• 年：2015
• 卷：55
• 期：1
• 页码：51-56
• 全文大小：183 KB
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• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Industrial Chemistry and Chemical Engineering
  Russian Library of Science
  
• 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
• ISSN：1555-6239

文摘

The kinetics of the reaction between cyclopentene and an aqueous solution of hydrogen peroxide under phase-transfer catalysis conditions has been studied. The activation energies of the successive stages of cyclopentene epoxidation to 1,2-epoxycyclopentane and the hydration of the resulting epoxide to 1,2-cyclopentanediol have been found, and the orders of the reactions with respect to the reactants have been determined. A mathematical model of the process that adequately describes the available experimental data in the entire range of reactant concentrations has been proposed.