Recycling of Secondary Tungsten Resources

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• 作者：Devabrata Mishra ; Shivendra Sinha…
• 关键词：Tungsten scrap ; Yellow tungsten oxide (YTO) ; Sodium tungstate ; Tungsten metal powder
• 刊名：Transactions of the Indian Institute of Metals
• 出版年：2017
• 出版时间：March 2017
• 年：2017
• 卷：70
• 期：2
• 页码：479-485
• 全文大小：
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Metallic Materials; Materials Science, general; Tribology, Corrosion and Coatings;
• 出版者：Springer India
• ISSN：0975-1645
• 卷排序：70

文摘

Tungsten and its alloys find critical applications in several important sectors, such as defence, aerospace, mining, manufacturing, telecommunications etc., which are key to economic development and national security. Global tungsten deposits are limited (~3.3 million tonnes) and highly localized; China dominates the supply with more than 84% share. India doesn’t have any economic tungsten ore deposits, and produces meagre quantities of tungsten in comparison to its demand of ~1500 tonne/year. In order to lessen the import burden and supply risk to the country’s defence programmes, India is required to focus on producing this important metal from various available secondary and lean grade resources such as scraps and tailings. This article presents some of the recently developed and commercialized tungsten recycling technologies by CSIR-NML, which include: (1) recycling of tungsten carbide (WC) hard metal scraps for production of high pure yellow tungsten oxide (WO₃) and W-metal powder; and (2) production of high pure sodium tungstate (Na₂WO₄·2H₂O) from spent hydro-refining catalysts. Besides describing the process flow-sheets and product specifications, the paper highlights the advantages of CSIR-NML technologies over the presently practiced technologies.