The study of firing of a ceramic body made from illite and fluidized bed combustion fly ash
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- 作者：Tomáš Húlan ; Anton Trník ; Tiit Kaljuvee…
- 关键词：Firing ; Fly ash ; Illitic ceramics ; Internal friction ; Mechanical strength ; Waste ; Young’s modulus
- 刊名：Journal of Thermal Analysis and Calorimetry
- 出版年：2017
- 出版时间：January 2017
- 年：2017
- 卷：127
- 期：1
- 页码：79-89
- 全文大小：
- 刊物类别：Chemistry and Materials Science
- 刊物主题：Physical Chemistry; Analytical Chemistry; Polymer Sciences; Inorganic Chemistry; Measurement Science and Instrumentation;
- 出版者：Springer Netherlands
- ISSN：1588-2926
- 卷排序：127
文摘
Fly ash from coal combusting thermal power plants is a serious problem from the point of view of its storing and pollution of the environment. Currently, thermal power plants change the combustion technology from pulverized firing to fluidized bed combustion. A promising reutilization of the fly ash from fluidized bed combustion (FFA) shows itself in the ceramic industry. In this paper, the influence of the FFA content in illite-based ceramics on its thermophysical and elastic properties was investigated during heating and cooling stages of firing. The samples are made from a mixture of the illitic clay (60 mass%), various portion of FFA (0–40 mass%) and grog (40–0 mass%). The impulse excitation technique is used for the determination of Young’s modulus and the internal friction. Analyses that included DTA, TG, thermodilatometry, XRD and SEM are used to obtain the better understanding of the development of the phase transformations in the samples. It is found that a higher amount of FFA in the sample leads to a higher mass loss at low temperatures, a higher mass loss due to the decomposition of calcite, a less intensive shrinkage after firing, a lower bulk density and lower Young’s modulus during firing above 800 °C and after cooling. After firing of the samples at 1100 °C, the mechanical strength and Young’s modulus decrease with the FFA content. A linear relationship between Young’s modulus and the mechanical strength is observed.