Syntheses of carboxymethylcellulose/graphene nanocomposite superabsorbent hydrogels with improved gel properties using electron beam radiation

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• 作者：Yoonki Sung ; Tak-Hyun Kim ; Byunghwan Lee
• 关键词：carboxymethylcellulose (CMC) ; electron beam ; graphite oxide (GO) ; nanocomposite superabsorbent hydrogels (NCSHs) ; reduced graphene oxide (rGO) ; superabsorbent hydrogels (SHs)
• 刊名：Macromolecular Research
• 出版年：2016
• 出版时间：February 2016
• 年：2016
• 卷：24
• 期：2
• 页码：143-151
• 全文大小：590 KB
• 参考文献：(1).1996 Protocol to the Convention on the Prevention of Marine Pollution by Dumping of Wastes and Other Matter (as amended in 2006).
  (2).M. J. Zohuriaan-Mehr and K. Kabiri, Iran. Polym. J., 17, 451 (2008).
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  (20).Y. J. Lee, G.-P. Kim, Y. Bang, J. Yi, J. G. Seo, and I. K. Song, Mater. Res. Bull., 50, 240 (2014).CrossRef
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• 作者单位：Yoonki Sung (1)
  Tak-Hyun Kim (2)
  Byunghwan Lee (1)
  
  1. Department of Chemical Engineering, Keimyung University, 1095 Dalgubeoldaero, Dalseo-Gu, Daegu, 42601, Korea
  2. Advanced Radiation Technology Institute, Korea Atomic Energy Research Institute, 29, Geumgu-gil, Jeongeup-si, Jeonbuk, 56212, Korea
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Physical Chemistry
  Polymer Sciences
  Characterization and Evaluation of Materials
  Soft and Granular Matter, Complex Fluids and Microfluidics
  Nanochemistry
  Nanotec
  
• 出版者：The Polymer Society of Korea, co-published with Springer
• ISSN：2092-7673

文摘

Nanocomposite superabsorbent hydrogels (NCSHs) were prepared via electron beam radiation-assisted polymerization using carboxymethylcellulose (CMC) and carbon materials as a superabsorbent polymer and additive inorganic nanomaterial, respectively. Carbon materials such as graphite oxide (GO), reduced graphene oxide (rGO), and activated carbon (AC) were used as additives. The chemical structure and morphology of the prepared NCSHs and pure superabsorbent hydrogels (SHs) were characterized using Fourier transform infrared spectroscopy and optical microscopy. In the prepared NCSHs, the carbon components were dispersed well in the CMC polymer matrix. The mechanical strength and gel fraction of the prepared materials were measured, and the swelling kinetics were evaluated using distilled water, urea solution, and physiological saline water. The prepared NCSHs using GO and rGO exhibited larger gel fraction and mechanical strength than the corresponding non-composite SHs. Electron beam radiation was more effective than solution polymerization in the syntheses of SHs and NCSHs with large gel fraction and high mechanical strength. The NCSHs prepared by electron beam radiation exhibited comparable swelling capabilities to those prepared by solution polymerization. Keywords carboxymethylcellulose (CMC) electron beam graphite oxide (GO) nanocomposite superabsorbent hydrogels (NCSHs) reduced graphene oxide (rGO) superabsorbent hydrogels (SHs) Page %P Close Plain text Look Inside Reference tools Export citation EndNote (.ENW) JabRef (.BIB) Mendeley (.BIB) Papers (.RIS) Zotero (.RIS) BibTeX (.BIB) Add to Papers Other actions Register for Journal Updates About This Journal Reprints and Permissions Share Share this content on Facebook Share this content on Twitter Share this content on LinkedIn Related Content Supplementary Material (0) References (22) References(1).1996 Protocol to the Convention on the Prevention of Marine Pollution by Dumping of Wastes and Other Matter (as amended in 2006).(2).M. J. Zohuriaan-Mehr and K. Kabiri, Iran. Polym. J., 17, 451 (2008).(3).R. Po, J. Macromol. Sci. C, C34, 607 (1994).CrossRef(4).K. M. El Salmawi and S. M. Ibrahim, Macromol. Res., 19, 1029 (2011).CrossRef(5).A. I. Raafat, M. Eid, and M. B. El-Arnaouty, Nucl. Instrum. Methods. B, 283, 71 (2012).CrossRef(6).K. Kabiri, H. Omidian, M. J. Zohuriaan-Mehr, and S. Doroudiani, Polym. Compos., 32, 277 (2011).CrossRef(7).H. Kim, A. A. Abdala, and C. W. Macosko, Macromolecules, 43, 6515 (2010).CrossRef(8).J. Qiu, L. Xu, J. Peng, M. Zhai, L. Zhao, J. Li, and G. Wei, Carbohydr. Polym., 70, 236 (2007).CrossRef(9).X. Ma, Y. Li, W. Wang, Q. Ji, and Y. Xia, Eur. Polym. J., 49, 389 (2013).CrossRef(10).Y. Huang, M. Zeng, J. Ren, J. Wang, L. Fan, and Q. Xu, Colloids Surf. A, 401, 97 (2012).CrossRef(11).A. K. Geim and K. S. Novoselov, Nat. Mater., 6, 183 (2007).CrossRef(12).A. K. Geim, Science, 324, 1530 (2009).CrossRef(13).B. Fei, R. A. Wach, H. Mitomo, F. Yoshii, and T. Kume, J. Appl. Polym. Sci., 78, 278 (2000).CrossRef(14).C. Chang, B. Duan, J. Cai, and L. Zhang, Eur. Polym. J., 46, 92 (2010).CrossRef(15).D. C. Marcano, D. V. Kosynkin, J. M. Berlin, A. Sinitskii, Z. Sun, A. Slesarev, L. B. Alemany, W. Lu, and J. M. Tour, ACS Nano, 4, 4806 (2010).CrossRef(16).H. C. Schniepp, J.-L. Li, M. J. McAllister, H. Sai, M. Herrera-Alonso, D. H. Adamson, R. K. Prud’homme, R. Car, D. A. Saville, and I. A. Aksay, J. Phys. Chem. B, 110, 8535 (2006).CrossRef(17).J. Kwon and B. Lee, Chem. Eng. Res. Des., 104, 519 (2015).CrossRef(18).I. Katime, A. Álvarez-Bautista, L. G. Guerrero-Ramírez, and E. Mendizábal, Topol. Supramol. Polym. Sci., 1, 17 (2014).(19).A. C. Ferrari, J. C. Meyer, V. Scardaci, C. Casiraghi, M. Lazzeri, F. Mauri, S. Piscanec, D. Jiang, K. S. Novoselov, S. Roth, and A. K. Geim, Phys. Rev. Lett., 97, 187401 (2006).CrossRef(20).Y. J. Lee, G.-P. Kim, Y. Bang, J. Yi, J. G. Seo, and I. K. Song, Mater. Res. Bull., 50, 240 (2014).CrossRef(21).H. M. N. El-Din, S. G. A. Alla, and A. W. M. El-Naggar, Radiat. Phys. Chem., 79, 725 (2010).CrossRef(22).R. A. Wach, H. Mitomo, F. Yoshii, and T. Kume, J. Appl. Polym. Sci., 81, 3030 (2001).CrossRef About this Article Title Syntheses of carboxymethylcellulose/graphene nanocomposite superabsorbent hydrogels with improved gel properties using electron beam radiation Journal Macromolecular Research Volume 24, Issue 2 , pp 143-151 Cover Date2016-02 DOI 10.1007/s13233-016-4020-x Print ISSN 1598-5032 Online ISSN 2092-7673 Publisher The Polymer Society of Korea Additional Links Register for Journal Updates Editorial Board About This Journal Manuscript Submission Topics Polymer Sciences Soft and Granular Matter, Complex Fluids and Microfluidics Physical Chemistry Characterization and Evaluation of Materials Nanochemistry Nanotechnology Keywords carboxymethylcellulose (CMC) electron beam graphite oxide (GO) nanocomposite superabsorbent hydrogels (NCSHs) reduced graphene oxide (rGO) superabsorbent hydrogels (SHs) Industry Sectors Pharma Materials & Steel Automotive Chemical Manufacturing Biotechnology Electronics IT & Software Telecommunications Consumer Packaged Goods Aerospace Oil, Gas & Geosciences Engineering Authors Yoonki Sung (1) Tak-Hyun Kim (2) Byunghwan Lee (1) Author Affiliations 1. Department of Chemical Engineering, Keimyung University, 1095 Dalgubeoldaero, Dalseo-Gu, Daegu, 42601, Korea 2. Advanced Radiation Technology Institute, Korea Atomic Energy Research Institute, 29, Geumgu-gil, Jeongeup-si, Jeonbuk, 56212, Korea Continue reading... To view the rest of this content please follow the download PDF link above.