Synthesis, microstructures and properties of amorphous poly(ethylene terephthalate-co- tricyclodecanedimethylene terephthalate)

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• 作者：Yuhsin Tsai ; Cheng-Hsing Fan ; Jyh-Horng Wu
• 关键词：Copolyester ; PET ; Amorphous ; Tricyclodecanedimethanol
• 刊名：Journal of Polymer Research
• 出版年：2016
• 出版时间：March 2016
• 年：2016
• 卷：23
• 期：3
• 全文大小：2,022 KB
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• 作者单位：Yuhsin Tsai (1)
  Cheng-Hsing Fan (2)
  Jyh-Horng Wu (2)
  
  1. School of Chinese Medicine, China Medical University, Taichung, Taiwan
  2. Materials and Chemical Research Laboratories, Industrial Technology Research Institute, Rm.427, 8, Gongyan Rd., Liujia District, Tainan, Taiwan
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Polymer Sciences
  Industrial Chemistry and Chemical Engineering
  Characterization and Evaluation Materials
  
• 出版者：Springer Netherlands
• ISSN：1572-8935

文摘

PET is one of the most important commercial polymers and much effort is being made to modify PET by melt copolymerization with a second glycol or diacid comonomer in a way that yields an amorphous material with a high Tg. In this study, various amounts (0–100 %) of tricyclodecanedimethanol (TCDDM) were used to copolymerize ethylene glycol and terephthalic acid to form a series of copolyesters (PETD). The compositions, microstructures, thermal behaviors, optical transmissions, mechanical properties, and gas transport properties of the copolymers are comprehensively examined over the entire range of copolymer compositions. The experimental results support the tuning of the properties of these copolymers by adjusting their composition. Therefore, they contribute to the design of new PET materials with a better balance among thermal, mechanical, optical, and gas transport properties. Keywords Copolyester PET Amorphous Tricyclodecanedimethanol