Synthesis and electrochemical properties of Li1.2Mn0.54Ni0.13Co0.13O2 cathode material for lithium-ion battery

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• 作者：ChenQiang Du ; Fei Zhang ; ChenXiang Ma ; JunWei Wu ; ZhiYuan Tang ; XinHe Zhang…
• 关键词：Lithium ; ion battery ; Lithium ; rich metal oxides ; Li1.2Mn0.54Ni0.13Co0.13O2 ; Solid ; state method
• 刊名：Ionics
• 出版年：2016
• 出版时间：February 2016
• 年：2016
• 卷：22
• 期：2
• 页码：209-218
• 全文大小：5,530 KB
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• 作者单位：ChenQiang Du (1)
  Fei Zhang (1)
  ChenXiang Ma (1)
  JunWei Wu (2)
  ZhiYuan Tang (1)
  XinHe Zhang (3)
  Deyang Qu (3) (4)
  
  1. Department of Applied Chemistry, School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300072, China
  2. School of Materials Science and Engineering, Harbin Institute of Technology Shenzhen Graduate School, Shenzhen, 518055, China
  3. McNair Technology Company, Limited, Dongguan City, Guangdong, 523700, China
  4. Department of Chemistry, University of Massachusetts Boston, 100 Morrissey Blvd., Boston, MA, 02125, USA
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Electrochemistry
  Materials Science
  Physical Chemistry
  Condensed Matter
  Renewable Energy Sources
  Electrical Power Generation and Transmission
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1862-0760

文摘

The layered Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ lithium-rich manganese-based solid solution cathode material has been synthesized by a simple solid-state method. The as-prepared material has a typical layered structure with R-3m and C2/m space group. The synthesized Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ has an irregular shape with the size range from 200 to 500 nm, and the primary particle of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ has regular sphere morphology with a diameter of 320 nm. Electrochemical performances also have been investigated. The results show that the cathode material Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ prepared at 900 °C for 12 h has a good electrochemical performance, which can deliver a high initial discharge capacity of 233.5, 214.2, 199.3, and 168.1 mAh g−1 at 0.1, 0.2, 0.5, and 1 C, respectively. After 50 cycles, the capacity retains 178.0, 166.3, 162.1, and 155.9 mAh g−1 at 0.1, 0.2, 0.5, and 1 C, respectively. The results indicate that the simple method has a great potential in synthesizing manganese-based cathode materials for Li-ion batteries. Keywords Lithium-ion battery Lithium-rich metal oxides Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ Solid-state method