Low-voltage electron-induced reaction of chlorobenzene in liquid phase

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• 作者：I. V. Bodrikov ; A. M. Kut’in ; E. Yu. Titov ; D. Yu. Titov…
• 关键词：low ; voltage electronic induction ; discharge ; liquid ; phase reactions of chlorobenzene ; benzene ; naphthalene ; anthracene ; phenylacetylene ; vinylnaphthalene ; chlorobiphenyl
• 刊名：High Energy Chemistry
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：51
• 期：1
• 页码：60-64
• 全文大小：
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Physical Chemistry;
• 出版者：Pleiades Publishing
• ISSN：1608-3148
• 卷排序：51

文摘

Pathways of chlorobenzene transformation in the liquid phase under low-voltage electron-induced discharges at an average temperature of 30°C have been studied. It has been found that the product composition of the chlorobenzene reaction in the case of copper electrodes depends on the voltage on the electrodes: benzene and phenylacetylene are produced at 30 V; benzene, phenylacetylene, naphthalene, and anthracene, at 40 V; and benzene, phenylacetylene, naphthalene, vinylnaphthalene, and chlorobiphenyl, at 60 V. In addition to the liquid products, acetylene, carbon black, and copper chlorides are formed during discharges.