Macrocycles for the complexation of radiocesium: a concise review of crystallographic and computational studies
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- 作者：Fabio Pichierri
- 关键词：137Cs ; Alkali metal ions ; Extraction of radionuclides ; Molecular structure ; Environmental computational chemistry
- 刊名：Journal of Radioanalytical and Nuclear Chemistry
- 出版年：2017
- 出版时间：February 2017
- 年：2017
- 卷：311
- 期：2
- 页码：1251-1263
- 全文大小：
- 刊物类别：Chemistry and Materials Science
- 刊物主题：Nuclear Chemistry; Physical Chemistry; Nuclear Physics, Heavy Ions, Hadrons; Diagnostic Radiology; Inorganic Chemistry;
- 出版者：Springer Netherlands
- ISSN：1588-2780
- 卷排序：311
文摘
We review the crystallographic studies concerned with the complexes between cesium and different types of macrocycles. A detailed examination of the molecular structures indicates that the formation of several cesium–oxygen bonds is necessary in order for the macrocyle to capture a single Cs+ ion. In some cases, additional interactions such as cesium–arene and cesium–fluorine interactions may operate either alone or in combination with the above chemical bonds. Computational quantum chemistry studies based on experimental crystal structures represent a useful aid for elucidating the mechanism of binding and the role that explicit water molecules have in establishing ion–dipole interactions or H-bonds with the Cs+-macrocycle complex.