Crystal structure of nitrate tris(4-allylthiosemicarbazide)-chromium(III) hydrate

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• 作者：Yu. M. Chumakov ; P. A. Petrenko ; V. O. Graur…
• 关键词：single crystal X ; ray diffraction analysis ; chromium coordination compounds ; 4 ; allylthiosemicarbazide
• 刊名：Journal of Structural Chemistry
• 出版年：2016
• 出版时间：January 2016
• 年：2016
• 卷：57
• 期：1
• 页码：202-205
• 全文大小：295 KB
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• 作者单位：Yu. M. Chumakov (1) (3)
  P. A. Petrenko (1)
  V. O. Graur (2)
  V. I. Tsapkov (2)
  A. P. Gulea (2)
  
  1. Institute of Applied Physics of Academy of Sciences of Moldova, Chisinau, Moldova
  3. Gebze Institute of Technology, Cayirova, Kocaeli, Turkey
  2. Moldova State University, Chisinau, Moldova
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Inorganic Chemistry
  Physical Chemistry
  Atoms, Molecules, Clusters and Plasmas
  Atomic and Molecular Structure and Spectra
  Solid State Physics and Spectroscopy
  Russian Library of Science
  
• 出版者：Springer New York
• ISSN：1573-8779

文摘

The crystal structure of nitrate tris(4-allylthiosemicarbazide)chromium(III) hydrate [CrL₃](NO₃)₃(H₂O)_1.05 (I), where L is 4-allylthiosemicarbazide, is determined. The asymmetric unit of the cell of the crystal structure of I contains a complex of a chromium ion with three bidentate coordinated molecules L. The outer coordination sphere of the central atom contains a disordered water molecule and three nitrate ions. The coordination polyhedron of the chromium atom in complex I is an octahedron. In the crystal, the complexes of the compound under study are joined with each other by the outer-sphere nitrato groups into a three-dimensional branched net of hydrogen bonds.