trans-dinitro- and trans-dinitratoruthenium complexes [RuNO(NH3)2(NO2)2(OH)] and [RuNO(NH3)2(H2O)(NO3)2]NO3¡¤H2O
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- 作者：M. A. Il¡¯in ; E. V. Kabin ; V. A. Emel¡¯yanov ; I. A. Baidina and V. A. Vorob¡¯yov
- 关键词：ruthenium ; nitroso complexes ; ammino complexes ; nitro complexes ; nitrato complexes ; spent nuclear fuel ; X ; ray analysis
- 刊名：Journal of Structural Chemistry
- 出版年：2009
- 出版时间：April, 2009
- 年：2009
- 卷：50
- 期：2
- 页码：328-334
- 全文大小：160.2 KB
文摘
Methods for the synthesis of trans-diammino complexes [RuNO(NH3)2(NO2)2(OH)] (I) and [RuNO(NH3)2(H2O)(NO3)2](NO3)¡¤H2O (II) are suggested. The compounds were studied by IR spectroscopy and X-ray phase and X-ray structural analyses. Crystal data: space group P-1; a = 6.2328(2) ?, b = 11.0488(3) ?, c = 11.0981(4) ?, α = 71.942(1)¡ã, β = 83.291(1)¡ã, γ = 86.877(1)¡ã (I); space group P21; a = 6.6290(2) ?, b = 13.4389(5) ?, c = 7.0180(2) ?, β 114.281(1)¡ã (II). Complex II readily lost some part of crystal water on storage in open air.