Low-temperature wave conversion of energetic compounds in filled condensed systems

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• 作者：Yu. M. Mikhailov (1)
  V. V. Aleshin (1) vva@icp.ac.ru
• 关键词：Key words low ; temperature wave conversion – ; filled condensed systems – ; energetic material – ; solid filler – ; polymeric binder – ; preparation – ; highly porous composite material – ; nano ; sized metal particles – ; catalytic material – ; combustion
• 刊名：Russian Chemical Bulletin
• 出版年：2011
• 出版时间：September 2011
• 年：2011
• 卷：60
• 期：9
• 页码：1802-1809
• 全文大小：475.2 KB
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• 作者单位：1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432 Chernogolovka, Moscow Region, Russian Federation
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Chemistry
  Organic Chemistry
  Inorganic Chemistry
  Russian Library of Science
  
• 出版者：Springer New York
• ISSN：1573-9171

文摘

The features of flameless low-temperature wave conversion (LWC) of some energetic materials in filled systems were studied experimentally and analyzed theoretically. The results attest to an relay-race mechanism of process propagation in the initial composition. An important role of the filling material in stabilization of the LWC wave of the energetic component is revealed. In the presence of mono- or oligomeric binders, flameless LWC of the energetic component affords strong highly porous composite materials. The possibility of using this method for preparing new high-performance grinding materials and catalysts containing nanosized particles of transition metals and their derivatives is demonstrated.