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作者单位:A. Allahdini (1) H. Yazdani Ahmadabadi (1) S. Rastegar (1) Z. Ranjbar (2) (3)
1. Faculty of Polymer Engineering and Color Technology, Amirkabir University of Technology, Hafez Street, Tehran, Iran 2. Department of Surface Coatings and Corrosion, Institute for Color Science and Technology, No. 55, Vafamanesh Street, Hossein Abad Square, Pasdaran, Tehran, Iran 3. Centre of Excellence for Color Science and Technology, Tehran, Iran
刊物类别:Chemistry and Materials Science
刊物主题:Chemistry Tribology, Corrosion and Coatings Surfaces and Interfaces and Thin Films Polymer Sciences Materials Science
出版者:Springer US
ISSN:1935-3804
文摘
In this work, the water uptake of crosslinked urethane-based coatings in high humidity conditions as a function of crosslinking temperature was investigated. The water uptake values were measured using an electrochemical impedance spectroscopy technique by applying the Brasher–Kingsbury procedure. Water uptake values as high as 200% were observed in the current research. These anomalous results were explained based on capillary condensation of diffused water molecules in the nano-metrically (or nano-scale) rough hydrophilic surfaces of the pores formed by thermal degradation of the polyurethane network. The water uptake value is at its minimum when an effectively pore-free tight network formed at moderate crosslinking conditions.