Capillary condensation-induced anomalous water sorption in urethane-based coatings exposed to high humidity conditions
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  • 作者:A. Allahdini ; H. Yazdani Ahmadabadi…
  • 关键词:Capillary condensation ; Crosslinking ; Water sorption ; Thermal degradation ; induced voids ; Humidity conditions ; Electrochemical impedance
  • 刊名:Journal of Coatings Technology and Research
  • 出版年:2016
  • 出版时间:March 2016
  • 年:2016
  • 卷:13
  • 期:2
  • 页码:299-306
  • 全文大小:3,126 KB
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  • 作者单位:A. Allahdini (1)
    H. Yazdani Ahmadabadi (1)
    S. Rastegar (1)
    Z. Ranjbar (2) (3)

    1. Faculty of Polymer Engineering and Color Technology, Amirkabir University of Technology, Hafez Street, Tehran, Iran
    2. Department of Surface Coatings and Corrosion, Institute for Color Science and Technology, No. 55, Vafamanesh Street, Hossein Abad Square, Pasdaran, Tehran, Iran
    3. Centre of Excellence for Color Science and Technology, Tehran, Iran
  • 刊物类别:Chemistry and Materials Science
  • 刊物主题:Chemistry
    Tribology, Corrosion and Coatings
    Surfaces and Interfaces and Thin Films
    Polymer Sciences
    Materials Science
  • 出版者:Springer US
  • ISSN:1935-3804
文摘
In this work, the water uptake of crosslinked urethane-based coatings in high humidity conditions as a function of crosslinking temperature was investigated. The water uptake values were measured using an electrochemical impedance spectroscopy technique by applying the Brasher–Kingsbury procedure. Water uptake values as high as 200% were observed in the current research. These anomalous results were explained based on capillary condensation of diffused water molecules in the nano-metrically (or nano-scale) rough hydrophilic surfaces of the pores formed by thermal degradation of the polyurethane network. The water uptake value is at its minimum when an effectively pore-free tight network formed at moderate crosslinking conditions.

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