The effect of the protonic component of conduction on the electrical properties of oxide glass
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- 作者：A. A. Pronkin ; I. V. Murin ; I. A. Sokolov
- 关键词：nature of the conduction of glass ; protonic conduction ; mixed protonic ; ionic conduction ; ionic conduction ; concentration dependence of the electric conduction ; oxide glass
- 刊名：Glass Physics and Chemistry
- 出版年：2015
- 出版时间：January 2015
- 年：2015
- 卷：41
- 期：1
- 页码：54-58
- 全文大小：159 KB
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文摘
A short review of works devoted to studying the effect of hydrogen-containing fragments of the structure (mainly H2O and OH?/sup>-groups) on the physicochemical (mainly electrical) properties of oxide glass has been presented. It was noted that the conduction of alkali-free oxide glass is due to the migration of protons. When introducing alkali metal oxides in their composition in the region of low Me2O concentrations, the electric current transport is due to the combined migration of protons and alkali metal ions; the conduction due to the migration of exclusively alkali ions is observed at concentrations of alkali metal ion oxides higher than 20 mol %. It was noted that in oxide glass containing ions of alkaline earth metals the conduction is also due to the migration of impurity protons. No participation of ions of alkaline earth metals in the electricity transport was observed.