Synthesis and properties of dithiophosphato-substituted aldehydes

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• 作者：M. B. Gazizov ; R. A. Khairullin ; N. G. Aksenov ; R. F. Karimova
• 关键词：O ; O ; dialkyl dithiophosphato) ; substituted aldehydes ; phosphorus ; containing acetals ; imines and hydrazones ; carboxylic acids ; trimethyland triethyl orthoformates ; acetals ; primary amines ; imines ; substituted hydrazines ; hydrazones ; phosphorus ; containing carboxylic acids
• 刊名：Russian Chemical Bulletin
• 出版年：2015
• 出版时间：January 2015
• 年：2015
• 卷：64
• 期：1
• 页码：237-240
• 全文大小：276 KB
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• 作者单位：M. B. Gazizov (1)
  R. A. Khairullin (1)
  N. G. Aksenov (1)
  R. F. Karimova (1)
  
  1. Kazan National Research Technological University, 68 ul. K. Marksa, 420015, Kazan, Russian Federation
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Chemistry
  Organic Chemistry
  Inorganic Chemistry
  Russian Library of Science
  
• 出版者：Springer New York
• ISSN：1573-9171

文摘

Hydrolysis of N-alkyl-2-dithiophosphatoaldiminium chlorides gives rise to new representatives of O,O-dialkyl dithiophosphato-substituted aldehydes, i.e., O,O-dialkyl S-(1,1-dimethyl-2-oxoethyl) dithiophosphates. Using reactions with trialkyl orthoformates, alkylamines, and substituted hydrazines, they were converted to the corresponding acetals, imines, and hydrazones. Their oxidation involves the aldehyde group to give a corresponding phosphoruscontaining carboxylic acid. The starting aldiminium salts were obtained by the reaction of N-alkyl-2-chloroaldimines with O,O-dialkyl dithiophosphoric acids. Keywords O,O-dialkyl dithiophosphato)-substituted aldehydes phosphorus-containing acetals imines and hydrazones carboxylic acids trimethyland triethyl orthoformates acetals primary amines imines substituted hydrazines hydrazones phosphorus-containing carboxylic acids