Synthesis of 4-(dibromomethyl)benzenecarbaldehyde and its reactions with N- and O-nucleophiles

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• 作者：M. B. Gazizov ; S. Yu. Ivanova ; R. F. Karimova ; L. R. Bagauva…
• 关键词：4 ; (dibromomethyl)benzenecarbaldehyde ; trimethyl phosphate ; preparation method ; acetals ; imines containing acetal group
• 刊名：Russian Chemical Bulletin
• 出版年：2016
• 出版时间：January 2016
• 年：2016
• 卷：65
• 期：1
• 页码：191-194
• 全文大小：230 KB
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Chemistry
  Organic Chemistry
  Inorganic Chemistry
  Russian Library of Science
  
• 出版者：Springer New York
• ISSN：1573-9171
• 卷排序：65

文摘

4-(Dibromomethyl)benzenecarbaldehyde was first synthesized and its preparation method jointly with terephthalic aldehyde was developed. Its reactions with O- and N-nucleophiles were studied: the reaction of this aldehyde with trialkyl orthoformates results in the formation of acetals while reacting with primary amines it forms imines, including those containing an additional acetal group.