Effect of the crystallization kinetic parameters on the structure and properties of a eutectic alloy of the LaB6–TiB2 system
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  • 作者:P. I. Loboda ; T. O. Soloviova ; Yu. I. Bogomol…
  • 关键词:reinforced composite material ; eutectic alloy ; lanthanum hexaboride ; titanium diboride ; centrifugal plasma sputtering ; microstructure ; mechanical properties
  • 刊名:Journal of Superhard Materials
  • 出版年:2015
  • 出版时间:November 2015
  • 年:2015
  • 卷:37
  • 期:6
  • 页码:394-401
  • 全文大小:5,473 KB
  • 参考文献:1.Loboda, P.I., Physicochemical principles of the development of novel boride materials for electronic engineering and elaboration of ceramic cathode units having enhanced efficiency, Dr. Sci. (Eng.) dissertation, Kiev: IPM, NASU, 2004.
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    3.Zagorodnya, E.V., Loboda, P.I., Bogomol, Yu.I., et al., Microstructure and mechanical properties of the LaB6-TiB2eutectic alloy produced by electric discharge sintering, Metal Phys. Advanced Technologies, 2011, vol. 33, pp. 351–360.
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    8.Loboda, P.I., Kysla, G.P., Bogomol, Yu.I., et al., Crystallization, structure, and properties of purposely crystallized eutectic alloys of boride pseudobinary systems, Theory and Practice Metallurgy, 2006, no. 4, pp. 123–125.
    9.Loboda, P., Features of structure formation with zone melting of powder boron-containing refractory materials, Powder Metall. Met. Ceram., 2000, no. 39(9-10), pp. 480–486.CrossRef
    10.Loboda, P.I., Bogomol, Yu.I., and Soloviova, T.O., Effect of mechanical vibrations on the formation of microstructures of single crystals and ceramic composites in the course of growing from a melt, Naukovi Visti NTUU KPI, 2013, no. 6, pp. 65–72.
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    12.Loboda,P.I., Bogomol, Yu.I., Zyma, R.A., et al., Effect of the aluminium doping on the microstructure and micromechanical properties of LaB6-TiB2 purposely crystallized eutectic alloys, Ibid., pp. 343-350.
    13.Orera, A., Pena, J.I., Serrano-Zabaleta, S., et al., Fibrillar Mn3O4-YMnSz well-ordered eutectics with potential functional applications, J. Eur. Ceram. Soc., 2015, no. 35, pp. 909–918.CrossRef
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    16.Loboda, P.I., Bogomol, Yu.I., and Shlyuko, V.Ya., Effect of boron additions on the sintering of powders of transition metals borides, Naukovi Visti NTUU KPI, 2001, no. 5, pp. 62–68.
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  • 作者单位:P. I. Loboda (1)
    T. O. Soloviova (1)
    Yu. I. Bogomol (1)
    D. O. Remizov (1)
    O. I. Bilyi (2)

    1. KPI, National Technical University of Ukraine, pr. Peremogy 37, Kiev, 03056, Ukraine
    2. E. Paton Institute of Electric Welding, National Academy of Sciences of Ukraine, vul. Antonovycha 56, Kiev, Ukraine
  • 刊物类别:Chemistry and Materials Science
  • 刊物主题:Chemistry
    Physical Chemistry
    Russian Library of Science
  • 出版者:Allerton Press, Inc. distributed exclusively by Springer Science+Business Media LLC
  • ISSN:1934-9408
文摘
The effect has been studied of the cooling rate and excess of boron on the formation of microstructures of LaB6–TiB2 reinforced ceramic composites during centrifugal sputtering in the argon atmosphere and during sputtering of the alloy melt onto a copper substrate in the helium atmosphere. It has been shown that the increase of the cooling rate to 106 deg/s results in a decrease of diameters of composite material fibers to 0.1–0.15 μm. The decrease of the boron concentration from 2 to 1 wt % has been found to lead to an increase of diameters and decrease of the number of the titanium diboride fibers by a factor of 2–3. Keywords reinforced composite material eutectic alloy lanthanum hexaboride titanium diboride centrifugal plasma sputtering microstructure mechanical properties

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