Anionic waterborne polyurethane dispersions from maleated cotton seed oil polyol carrying ionisable groups
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- 作者：Sashivinay Kumar Gaddam ; Aruna Palanisamy
- 关键词：Cottonseed oil ; Maleated polyol ; Polyurethane dispersion ; Ionic content
- 刊名：Colloid & Polymer Science
- 出版年：2016
- 出版时间：February 2016
- 年：2016
- 卷：294
- 期：2
- 页码：347-355
- 全文大小：1,284 KB
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Aruna Palanisamy (1)
1. Polymers and Functional Materials Division, Indian Institute of Chemical Technology, Hyderabad, 500007, Telangana State, India - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Polymer Sciences
Physical Chemistry
Soft Matter and Complex Fluids
Characterization and Evaluation Materials
Food Science - 出版者：Springer Berlin / Heidelberg
- ISSN：1435-1536
文摘
A novel class of bio-based, DMPA free, catalyst free, anionic waterborne polyurethane dispersions (PUD) have been successfully synthesized. Hydroxylated cottonseed oil has been maleated using maleic anhydride to introduce hydroxyl groups and ionisable carboxyl groups. This maleated polyol (MAHCSO) has been employed to develop water-based polyurethane dispersions through a prepolymer method and chain extension with dihydrazides at the dispersion stage. The –OH groups of the MAHCSO formed urethane bonds, and the carboxylate groups acted as an internal ionizer to stabilize the polymer dispersion in water. The significant effect of the ionic content in the polyol (MAHCSO) and chain length of dihydrazide on particle size, physico-chemical, thermal and mechanical properties of the resulting PUD films were investigated. Keywords Cottonseed oil Maleated polyol Polyurethane dispersion Ionic content