Interfacial insights on the dibenzo-based crown ether assisted cesium extraction in [BMIM][Tf2N]–water binary system
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- 作者：Rima Biswas ; Viswanath Pasumarthi…
- 关键词：Liquid–liquid extraction ; Crown ethers ; Cesium ; Ionic liquid ; Distribution coefficients ; MD simulation
- 刊名：Journal of Radioanalytical and Nuclear Chemistry
- 出版年：2017
- 出版时间：January 2017
- 年：2017
- 卷：311
- 期：1
- 页码：427-438
- 全文大小：
- 刊物类别：Chemistry and Materials Science
- 刊物主题：Nuclear Chemistry; Physical Chemistry; Nuclear Physics, Heavy Ions, Hadrons; Diagnostic Radiology; Inorganic Chemistry;
- 出版者：Springer Netherlands
- ISSN：1588-2780
- 卷排序：311
文摘
The distribution coefficient of Cs is estimated using dibenzo-21-crown-7 (DB21C7) and di-benzo-18-crown-6 (DB18C6) in 1-butyl-3-methylimidazolium bis (trifluroromethanesulphonyl) imide (BMIMTF2N) ionic liquid by performing solvent extraction experiments. In addition, molecular dynamics studies on the extraction of cesium (Cs+) ion transfer from the aqueous phase to the BMIMTF2N phase is reported. The experimental findings gave a cesium distribution coefficient of 0.218 and 0.326, which agrees closely with the values of 0.2 and 0.5 obtained from MD simulation for the ionophores DB18C6 and DB21C7, respectively. Thus MD simulation may be helpful in screening the solvents prior to the experiments.