Clinopyroxene in postshield Haleakala ankaramite: 1. Efficacy of thermobarometry

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• 作者：Julia Hammer ; Samantha Jacob ; Benoit Welsch…
• 关键词：Ocean island volcanism ; Clinopyroxene ; Thermobarometry ; Sector zoning
• 刊名：Contributions to Mineralogy and Petrology
• 出版年：2016
• 出版时间：January 2016
• 年：2016
• 卷：171
• 期：1
• 全文大小：6,301 KB
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• 作者单位：Julia Hammer (1)
  Samantha Jacob (1)
  Benoit Welsch (1)
  Eric Hellebrand (1)
  John Sinton (1)
  
  1. Department of Geology and Geophysics, University of Hawaii, Honolulu, HI, USA
  
• 刊物类别：Earth and Environmental Science
• 刊物主题：Earth sciences
  Geology
  Mineral Resources
  Mineralogy
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1432-0967

文摘

Magma storage depth is a fundamental aspect of a volcano鈥檚 magmatic plumbing system that may be resolved using mineral-melt thermobarometry, assuming crystal growth occurs at near-equilibrium conditions. We acquire major and minor element compositional analyses of whole rock, groundmass separates, and clinopyroxene in ankaramite erupted ca. 214 ka at Haleakala volcano to evaluate the efficacy of thermobarometry. Using various thermometer and barometer combinations, we obtain values of crystallization pressure (60鈥?500 MPa) that are generally consistent with those of previous studies, but find that the models most successful at recovering the conditions of relevant equilibrium experiments yield values at the low end of this range (鈮?50 MPa). We use quantitative EPMA spot analyses to transform X-ray element intensity maps into metal oxide concentrations maps and to produce qualitative pressure maps of whole crystals. The spatial context provided by this procedure reveals two compositionally distinct domain types not evident in the spot analysis data set, with median Na₂O contents differing by up to 26 % between domains. Na-rich domains represent putative crystallization pressures that are up to 365 MPa higher than Na-poor domains, within individual crystals. The presence of Na-rich domains associated with euhedral facets in contact with matrix is not consistent with concentric growth at near-equilibrium conditions of decreasing pressure, but rather co-crystallization of both domains under conditions of partial disequilibrium. Conservatively assuming that low-Na regions are less prone to kinetic partitioning, crystallization pressures for the Haleakala ankaramite correspond to crustal levels. We conclude that the reservoir supplying postshield eruptions at Haleakala has not deepened into the mantle, as was reported in a previous application of clinopyroxene thermobarometry to Haleakala鈥檚 postshield magma (Chatterjee et al. 2005). Keywords Ocean island volcanism Clinopyroxene Thermobarometry Sector zoning