Competitive adsorption

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• 作者：V. M. Gun’ko
• 关键词：multicomponent competitive adsorption ; equilibrium adsorption ; dynamic adsorption ; surface reactions ; multicomponent adsorption theory
• 刊名：Theoretical and Experimental Chemistry
• 出版年：2007
• 出版时间：May, 2007
• 年：2007
• 卷：43
• 期：3
• 页码：139-183
• 全文大小：555 KB
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Chemistry
  Russian Library of Science
  
• 出版者：Springer New York
• ISSN：1573-935X

文摘

A review is presented on the multicomponent competitive adsorption, static equilibrium adsorption, and dynamic nonequilibrium adsorption from gaseous and liquid media onto the surface of porous and disperse solids. The state of the theory of multicomponent adsorption is analyzed. Not only traditional methods were used for investigations in this field but also NMR spectroscopy (difference in the spectra of adsorbed and free compounds), FTIR spectroscopy (difference in the spectra of surface groups and bonds in adsorbates), calorimetry, thermally stimulated depolarization, photon correlation spectroscopy, electrophoresis, and cryoporometry.