Estimating the melting temperature of macromolecular poly-3,3-bis-(azidomethyl)oxetane

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• 作者：A. E. Golubev ; K. V. Pochivalov ; Ya. V. Kudryavtsev…
• 刊名：Polymer Science Series A
• 出版年：2015
• 出版时间：November 2015
• 年：2015
• 卷：57
• 期：6
• 页码：723-728
• 全文大小：253 KB
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• 作者单位：A. E. Golubev (1)
  K. V. Pochivalov (2)
  Ya. V. Kudryavtsev (3)
  M. Yu. Yurov (2)
  T. N. Lebedeva (2)
  A. E. Zavadskii (4)
  
  1. Research Institute of Polymer Materials, Chistopol’skaya ul. 16, Perm, 614113, Russia
  2. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Akademicheskaya ul. 1, Ivanovo, 153045, Russia
  3. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninskii pr. 29, Moscow, 119991, Russia
  4. Ivanovo State University of Chemistry and Technology, pr. Sheremetevskii 7, Ivanovo, 153000, Russia
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Polymer Sciences
  Russian Library of Science
  
• 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
• ISSN：1555-6107

文摘

A melting temperature of 90.4°C (complete amorphization) for macromolecular poly-3,3-bis(azidomethyl)oxetane is determined via the hydrostatic-weighing method. This value corresponds to the end of the endothermic peak of the DSC thermogram and is ~10°C higher than the maximum value. The amorphization of the polymer is found to proceed mainly owing to thermomechanical destruction of the crystallites, and only a very small part of them is melted purely thermally at the temperature of complete amorphization. The melting temperature is significantly reduced in the presence of the oligomer fraction in the polymer. The density and equilibrium heat of fusion of the crystalline regions, which coincide for various polymer samples, are found with consideration for the data of X-ray scattering. Original Russian Text ? A.E. Golubev, K.V. Pochivalov, Ya.V. Kudryavtsev, M.Yu. Yurov, T.N. Lebedeva, A.E. Zavadskii, 2015, published in Vysokomolekulyarnye Soedineniya. Ser. A, 2015, Vol. 57, No. 6, pp. 504-10.