Crystal structure of the ionic bioctahedral cluster complex [Ni(NH3)6]2.5NH4[Re12CS _{详细信息    查看全文}

• 作者：Ya. M. Gaifulin (12027)
  A. I. Smolentsev (12027)
  Yu. V. Mironov (12027)
  
• 关键词：rhenium ; bioctahedral cluster complex ; nickel ; crystal structure
• 刊名：Journal of Structural Chemistry
• 出版年：2013
• 出版时间：March 2013
• 年：2013
• 卷：54
• 期：2
• 页码：459-461
• 全文大小：167KB
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• 作者单位：Ya. M. Gaifulin (12027)
  A. I. Smolentsev (12027)
  Yu. V. Mironov (12027)
  
  12027. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia
  
• ISSN：1573-8779

文摘

A rhenium cluster complex [Ni(NH3)6]2.5·NH4[Re12CS17(CN)6]·8.5H2O is obtained and structurally described. The compound crystallizes in the triclinic space group P-1 with the unit cell parameters: a = 11.0856(13) ?, b = 15.242(2) ?, c = 21.232(3) ?, α = 90.158(4)°, β = 97.439(4)°, γ = 90.051(4)°, V = 3557.3(8) ?3, Z = 2, d calc = 3.287 g/cm3. The crystal structure represents a packing of [Ni(NH3)6]2+ and NH4 + cations, [Re12CS17(CN)6]6?/sup> cluster anions, and crystallization water molecules bound by a system of hydrogen bonds.