The electrodeposition of Zn-Ti alloys from ZnCl2-urea deep eutectic solvent

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• 作者：Cunying Xu (1)
  Qing Wu (1)
  Yixin Hua (1)
  Jian Li (1)
  
• 关键词：Electrodeposition ; Zn ; Ti alloys ; TiCl4 ; Deep eutectic solvent
• 刊名：Journal of Solid State Electrochemistry
• 出版年：2014
• 出版时间：August 2014
• 年：2014
• 卷：18
• 期：8
• 页码：2149-2155
• 全文大小：932 KB
• 参考文献：1. Wilcox GD, Gabe DR (1993) Corr Sci 35:1251-258 CrossRef
  2. Pletcher D (1984) Industrial electrochemistry. Chapman and Hall, London CrossRef
  3. Buzzeo MC, Evans RG, Compton RG (2004) Chem Phys Chem 5:1106-120 CrossRef
  4. Zein El Abedin S, Endres F (2006) Chem Phys Chem 7:58-1 CrossRef
  5. Mukhopadhyay I, Freyland W (2003) Langmuir 19:1951-953 CrossRef
  6. Pradhan D, Reddy RG (2009) Electrochim Acta 54:1874-880 CrossRef
  7. Carlin RT, Osteryoung RA, Wilkes JS, Rovang J (1990) Inorg Chem 29:3003-009 CrossRef
  8. Tsuda T, Hussey CL, Stafford GR, Bonevich JE (2003) J Electrochem Soc C 150:234-43 CrossRef
  9. Ali MR, Nishikata A, Tsuru T (2003) Indian J Chem Technol 10:21-6
  10. Mukhopadhyay I, Aravinda CLR, Borissov D, Freyland W (2005) Electrochim Acta 50:1275-281 CrossRef
  11. Endres F, Zein El Abedin S, Saad AY, Moustafa EM, Borissenko N, Price WE, Wallace GG, MacFarlane DR, Newmanc PJ, Bund A (2008) Phys Chem Chem Phys 10:2189-199 CrossRef
  12. Pana SJ, Tsaia WT, Sun IW (2010) Electrochem Solid-State Lett D 13:69-1 CrossRef
  13. Chen PY, Hussey CL (2007) Electrochim Acta 52:1857-864 CrossRef
  14. Huang JF, Sun IW (2004) J Electrochem Soc C 151:8-5 CrossRef
  15. Borissov JD, Pareek A, Renner FU, Rohwerder M (2010) Phys Chem Chem Phys 12:2059-062 CrossRef
  16. Lin MC, Chen PY, Sun IW (2001) J Electrochem Soc C 148:653-58 CrossRef
  17. Clare B, Sirwardana A, MacFarlane DR (2009) Top Curr Chem 290:1-0 CrossRef
  18. Wasserscheid P, Welton T (2002) Ionic liquids in synthesis. Wiley-VCH, Weinheim CrossRef
  19. Abbott AP, Barron JC, Ryder KS, Wilson D (2007) Chem–Eur J 13:6495-501
  20. Fletcher S, Halliday CS, Gates D, Westcott M, Lwin T, Nelson G (1983) J Electroanal Chem Interfacial Electrochem 159:267-85 CrossRef
  21. Nicholson RS (1966) Anal Chem 38:1406-406 CrossRef
  22. Nicholson RS, Shain I (1964) Anal Chem 36:706-23 CrossRef
  23. Brenner A (1963) Electrodeposition of alloys: principles and practice. Academic Press, New York
  24. Leone GL, Niessen P, Rerr HW (1975) Metall Trans B 6:503-11 CrossRef
  
• 作者单位：Cunying Xu (1)
  Qing Wu (1)
  Yixin Hua (1)
  Jian Li (1)
  
  1. Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming, 650093, People’s Republic of China
  
• ISSN：1433-0768

文摘

The electrochemical behavior of Ti(IV) and the electrodeposition of Zn-Ti alloys were investigated in a ZnCl2-urea (1:3 molar ratio) deep eutectic solvent containing 0.27?mol?L? TiCl4. The electrochemical reduction of Ti(IV) to Ti was complicated by the formation of intermediate oxidation states of Ti(III) and Ti(II), as well as the precipitation of TiCl3. It was possible to prepare Zn-Ti alloys containing 5.8-6.7?at.% Ti. The composition and surface morphology of Zn-Ti alloys depended on deposition potential and temperature. The deposits could be indexed to a disordered hexagonal close-packed structure similar to pure Zn and were completely chloride-free. The current efficiency for the deposition of Zn-Ti alloys varied from 38.4 to 67.9?%.