Fabrication of optochemical and electrochemical sensors using thin films of porphyrin and phthalocyanine derivatives

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• 作者：PALANISAMY KALIMUTHU (1)
  ARUMUGAM SIVANESAN (1)
  S ABRAHAM JOHN (1)
  
• 关键词：Meso ; substituted porphyrin ; optochemical sensing ; HCl gas ; 1 ; 8 ; 15 ; 22 ; tetraaminometallophthalocyanine ; L ; cysteine
• 刊名：Journal of Chemical Sciences
• 出版年：2012
• 出版时间：November 2012
• 年：2012
• 卷：124
• 期：6
• 页码：1315-1325
• 全文大小：646KB
• 参考文献：1. Khairutdinov R F and Serpone N 1999 / J. Phys. Chem. B 103 761 CrossRef
  2. Baraldi I, Carnevali A, Ponterini G and Vanossi D 1995 / J. Mol. Struct. (Theochem) 333 121 CrossRef
  3. Supriyatno H, Yamashita M, Nakagawa K and Sadaoka Y 2002 / Sens. Actuators B: Chem. 85 197 CrossRef
  4. Luca G, Pollicino G, Romeo A, Scolaro L M 2006 / Chem. Mater. 18 2005 CrossRef
  5. Itagaki Y, Deki K, Nakashima S and Sadaoka Y 2006 / Sens. Actuators B: Chem. 117 302 CrossRef
  6. Nakagawa K, Sadaoka Y, Supriyatno H, Kubo A, Tsutsumi C and Tabuchi K 2001 / Sens. Actuators B: Chem. 76 42 CrossRef
  7. Nakagawa K, Kumon K, Tsutsumi C, Tabuchi K, Kitagawa T and Sadaoka Y 2000 / Sens. Actuators B: Chem. 65 138 CrossRef
  8. Supriyatno H, Yamashita M, Nakagawa K and Sadaoka Y 2002 / Sens. Actuators B: Chem. 85 197 CrossRef
  9. Nakagawa K, Kitagawa T and Sadaoka Y 1998 / Sens. Actuators B: Chem. 52 10 CrossRef
  10. Nakagawa K, Tanaka K, Kitagawa T and Sadaoka Y 1998 / J. Mater. Chem. 8 1199 CrossRef
  11. Itagaki Y, Deki K, Nakashima S I and Sadaoka Y 2005 / Sens. Actuators B: Chem. 1 393 CrossRef
  12. Sobbi A K, Wohrle D and Schlettwein D 1993 / J. Chem. Soc. Perkin Trans. II 481
  13. Stillman M J and Nyokong T 1989 In: / Phthalocyanines: Properties and applications, Leznoff C C and Lever A?B?P (eds), New York: VCH Publishers, Vol. 1
  14. Huang J, Virji S, Weiller B H and Kaner R B 2003 / J. Am. Chem. Soc. 125 125
  15. Adhikari B and Majumdar S 2004 / Prog. Polym. Sci. 29 699 CrossRef
  16. Collins R A and Mohammed K A 1988 / J. Phys. D: Appl. Phys. 21 154 CrossRef
  17. Zagal J, Bedioui F and Dodelet J P (eds) 2006 / N4-macrocyclic metal complexes, New York: Springer
  18. Bao Z, Lovinger A J and Dodabalapur A 2006 / Appl. Phys. Lett. 69 3066 CrossRef
  19. Lin C L, Lee C C and Ho K C 2002 / J. Electroanal. Chem. 81 524
  20. Somani P R and Radhakrishnan S 2003 / Mater. Chem. Phys. 77 117 CrossRef
  21. McKeown N B 1998 / Phthalocyanine materials: Synthesis, structure and function, Cambridge: Cambridge University Press
  22. Gu D, Chen Q, Tang X, Gan F, Shen S, Liu K and Xu H 1995 / Opt. Commun. 121 125 CrossRef
  23. Singerski R, Kalinowski J, Davoli I and Stizza S 1991 / Phys. Status Solidi A 125 597 CrossRef
  24. Bonnett R 1995 / Chem. Soc. Rev. 24 19 CrossRef
  25. Wohrle D, Kaune H, Schumann B and Jaeger N 1986 / Macromol. Chem. Phys. 187 2947 CrossRef
  26. Sivanesan A and John S A 2008 / Electrochim. Acta 53 6629 CrossRef
  27. Simpson T R E, Cook M J, Petty M C, Thorpe S C and Russell D A 1996 / Analyst 121 1501 CrossRef
  28. Cook M J 1996 / J. Mater. Chem. 6 677 CrossRef
  29. Cheng Z H, Gao L, Deng Z T, Jiang N, Liu Q, Shi D X, Du S X, Guo H M and Gao H J 2007 / J. Phys. Chem. C. 111 9240 CrossRef
  30. Kalyuzhny G, Vaskevich A, Ashkenasy G, Shanzer A and Rubinstein I 2000 / J. Phys. Chem. B 104 8238 CrossRef
  31. Lindsey J S and Wagner R W 1989 / J. Org. Chem. 54 828 CrossRef
  32. Sivanesan A and John S A 2008 / Langmuir 24 2186 CrossRef
  33. Tonezzer M, Quaranta A, Maggioni G, Carturan S and Della Mea G 2007 / Sens. Actuators B: Chem. 122 620 CrossRef
  34. Chen H T, Liu B, Wang H T, Xiao Z D, Chen M and Qian D 2007 / J Mater. Sci. Eng. C 27 639 CrossRef
  35. Knyukshto V N, Solovyov K N and Egorova G D 1998 / Biospectroscopy 4 121 CrossRef
  36. Christian G D 2004 / Analytical chemistry, sixth ed., Singapore: John Wiley & Sons
  37. Sehlotho N and Nyokong T 2006 / Electrochim. Acta 51 4463 CrossRef
  38. Sivanesan A and John S A 2009 / Electrochim. Acta 54 7458 CrossRef
  39. Huethorst J A M S and Fokkink L G J 1995 / Langmuir 11 2237 CrossRef
  40. Tse Y H, Janda P, Lam H, Zhang J, Pietro W J and Lever A B P 1997 / J. Porphyrins Phthalocyanines 1 3 CrossRef
  41. Janda P, Kobayashi N, Auburn P R, Lam H, Leznoff C?C and Lever A B P 1989 / Can. J. Chem. 67 1109 CrossRef
  42. Vijaikanth V, Capon J F, Gloaguen F, Schollhammer P, Talarmin J 2005 / Electrochem. Commun. 7 427 CrossRef
  43. Maree S and Nyokong T 2000 / J. Electroanal. Chem. 492 120 CrossRef
  44. Mashazi P N, Ozoemena K I, Maree D M and Nyokong T 2006 / Electrochim. Acta 51 3489 CrossRef
  45. Kalimuthu P and John S A 2009 / Electrochem. Commun. 11 367 CrossRef
  
• 作者单位：PALANISAMY KALIMUTHU (1)
  ARUMUGAM SIVANESAN (1)
  S ABRAHAM JOHN (1)
  
  1. Centre for Nanoscience and Nanotechnology, Department of Chemistry, Gandhigram Rural Institute, Gandhigram, Dindigul, 634 302, India
  
• ISSN：0973-7103

文摘

This paper describes the fabrication of thin films of porphyrin and metallophthalocyanine derivatives on different substrates for the optochemical detection of HCl gas and electrochemical determination of L-cysteine (CySH). Solid state gas sensor for HCl gas was fabricated by coating meso-substituted porphyrin derivatives on glass slide and examined optochemical sensing of HCl gas. The concentration of gaseous HCl was monitored from the changes in the absorbance of Soret band. Among the different porphyrin derivatives, meso- tetramesitylporphyrin (MTMP) coated film showed excellent sensitivity towards HCl and achieved a detection limit of 0.03ppm HCl. Further, we have studied the self-assembly of 1,8,15,22-tetraaminometallophthalocyanine (4α-MTAPc; M = Co and Ni) from DMF on GC electrode. The CVs for the self-assembled monolayers (SAMs) of 4α-CoIITAPc and 4α-NiIITAPc show two pairs of well-defined redox couple corresponding to metal and ring. Using the 4α-CoIITAPc SAM modified electrode, sensitive and selective detection of L-cysteine was demonstrated. Further, the SAM modified electrode also successfully separates the oxidation potentials of AA and CySH with a peak separation of 320mV. Graphical Abstract Thin films of meso-tetramesitylporphyrin on glass slide and 1,8,15,22-tetraaminometallophthalocyanine on GC electrode were fabricated for the optochemical detection of HCl gas and electrochemical determination of L-cysteine.