Theories and Models of Ion Diffusion
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  • 刊名:Topics in Applied Physics
  • 出版年:2017
  • 出版时间:2017
  • 年:2017
  • 卷:132
  • 期:1
  • 页码:9-60
  • 全文大小:1,253 KB
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  • 作者单位:Junko Habasaki (7)
    Carlos León (8)
    K. L. Ngai (9)

    7. Tokyo Institute of Technology, Yokohama, Kanagawa, Japan
    8. Facultad de Fisica, Universidad Complutense Madrid, Madrid, Spain
    9. IPCF, CNR, Pisa, Italy
  • 丛书名:Dynamics of Glassy, Crystalline and Liquid Ionic Conductors
  • ISBN:978-3-319-42391-3
  • 刊物类别:Physics and Astronom
  • 刊物主题:Physics
    Magnetism and Magnetic Materials
    Optical and Electronic Materials
    Laser Technology and Physics and Photonics
    Quantum Computing, Information and Physics
    Applied Optics, Optoelectronics and Optical Devices
    Solid State Physics and Spectroscopy
    Condensed Matter
  • 出版者:Springer Berlin / Heidelberg
  • 卷排序:132
文摘
This chapter describes some models that are often used in trying to understand experimental data and fundamental questions in ion diffusion in ionically conducting materials. The basics of linear response theory are introduced first, with the definition of the linear response function, the Kramers-Kronig relations, and the Fluctuation-Dissipation theorem. A second section is devoted to present the Debye model and several other phenomenological descriptions of dielectric relaxation in materials whose electrical response is dominated by bound charges. This helps to understand the conductivity relaxation that occurs in materials with mobile charges like ionic conductors, and to introduce the so called conductivity formalism and electric modulus formalism for the analysis of experimental data of ion diffusion dynamics. A simple model of ion hopping is introduced that accounts for the thermally activated behavior often found in ionic conductivity data. The relationship between non-Debye relaxation and non-Gaussianity of the dynamics in the real space is also discussed in this chapter. Finally, three different models for ion diffusion are described in some detail. These are the Random Barrier Model, the MIGRATION concept, and the Coupling Model.

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