参考文献:1. Nakamura S. The roles of structural imperfections in InGaN-based blue light-emitting diodes and laser diodes. Science, 1998, 281: 956-61 CrossRef 2. Brown S A, Reeves R J, Haase C S. Reactive-ion-etched gallium nitride: Metastable defects and yellow luminescence. Appl Phys Lett, 1999, 75(21): 3285-287 CrossRef 3. Morales A M, Lieber C M. A laser ablation method for the synthesis of crystalline semiconductor nanowires. Science, 1998, 279(5348): 208-11 CrossRef 4. Han W Q, Fan S S, Li Q Q, et al. Synthesis of galliium nitride nanorods through a carbon nanotube-confined reaction. Science, 1997, 277: 1287-289 CrossRef 5. Cheng G S, Chen S H, Zhu X G, et al. Highly ordered nanostructures of single-crystalline GaN nanowires. Mater Sci & Eng: A, 2000, 286: 165-68 CrossRef 6. Lyu S C, Cha O H, Suh E K, et al. Catalytic synthesis and photo-luminescence of gallium nitride nanowires. J Chem Phys Lett, 2003, 367: 136-40 CrossRef 7. He M, Minus I, Zhou P, et al. Growth of large-scale GaN nanowires and tubes by direct reaction of Ga with NH3. Appl Phys Lett, 2000, 77: 3731-733 CrossRef 8. Huang Y, Duan X, Cui Y, et al. Logic gates and computation from assembled nanowire building blocks. Science, 2001, 294(5545): 1313-317 CrossRef 9. Boo J H, Rohr C, Ho W. MOCVD of BN and GaN thin films on silicon: new attempt of GaN growth with BN buffer layer. J Crystal Growth, 1998, 189/190: 439-44 CrossRef 10. Dong Z, Xue C, Zhuang H, et al. Synthesis of three kinds of GaN nanowires through Ga2O3 films-reaction with ammonia. Phys E, 2005, 27: 32-7 CrossRef 11. Sun Y, Miyasato T, Wigmore J K. Characterization of excess carbon in cubic SiC films by infrared absorption. J Appl Phys, 1999, 85: 3377-379 CrossRef 12. Melendez-Lira M, Menendez J, Kramer K M, et al. Substitutional carbon in Si1-y Cy alloys as measured with infrared absorption and Raman spectroscopy. J Appl Phys, 1997, 82: 4246-252 CrossRef 13. Meng G W, Zhang L D, Qin Y, et al. Synthesis of β-SiC nanowires with SiO2 wrappers. Nanostructured Materials, 1999, 12: 1003-006 CrossRef 14. Ridley B K. Quantum Process in Semiconductors. Oxford: Clarendon, 1982. 62-6 15. Monemar B. Fundamental energy gap of GaN from photoluminescence excitation spectra. Phys Rev B, 1974, 10: 676-81 CrossRef 16. Chen C C, Yeh C H, Chen C H, et al. Catalytic growth and characterization of gallium nitride nanowires. J Am Chem Soc, 2001, 123: 2791-798 CrossRef
作者单位:Chengshan Xue (1) Yuxin Wu (1) Huizhao Zhuang (1) Deheng Tian (1) Yi’an Liu (1) Jianting He (1) Yujie Ai (1) Lili Sun (1) Fuxue Wang (1)
1. Institute of Semiconductors, College of Physics and Electronics, Shandong Normal University, Jinan, 250014, China
ISSN:1861-9541
文摘
GaN nanowires were successfully prepared on Si(111) substrate through ammoniating Ga2O3/BN films deposited by radio frequency magnetron sputtering system. The synthesized nanowires were confirmed as hexagonal wurtzite GaN by X-ray diffraction, selected-area electron diffraction and Fourier transform infrared spectra. Scanning electron microscopy and transmission electron microscopy revealed that the grown GaN nanowires have a smooth and clean surface with diameters ranging from 40 to 160 nm and lengths typically up to several tens of micrometers. The representative photoluminescence spectrum at room temperature exhibited a strong UV light emission band centered at 363 nm and a relative weak purple light emission peak at 422 nm. The growth mechanism is discussed briefly.