The safety of synthetic zeolites used in detergents
详细信息    查看全文
  • 作者:Claudia Fruijtier-P?lloth (1)
  • 关键词:Synthetic zeolites ; Laundry detergents ; Builders ; Safety ; Exposure
  • 刊名:Archives of Toxicology
  • 出版年:2009
  • 出版时间:January 2009
  • 年:2009
  • 卷:83
  • 期:1
  • 页码:23-35
  • 全文大小:653KB
  • 参考文献:1. A.I.S.E. (2000) Association Internationale de la Savonnerie, de la Détergence et des Produits d’Entretien, Industrial and Institutional Sector. Environmental dossier on professional laundry
    2. A.I.S.E. (2002) Association Internationale de la Savonnerie, de la Détergence et des Produits d’Entretien, Industrial and Institutional Sector. Habits & Use Table for Western Europe
    3. Bajpai D, Tyagi VK (2007) Laundry detergents: an overview. J Oleo Sci 56:327-40
    4. Benke GM, Osborn TW (1979) Urinary silicon excretion by rats following oral administration of silicon compounds. Food Cosmet Toxicol 17:123-27 CrossRef
    5. BfR (2005) Bundesinstitut für Risikobewertung [Federal Institute for Risk Assessment]. ?rztliche Mitteilungen bei Vergiftungen 2005. Dokumentations- und Bewertungsstelle für Vergiftungen des BfR. ISBN 3-938163-17-8
    6. BfR (2007) Bundesinstitut für Risikobewertung [Federal Institute for Risk Assessment]. Introduction to the problems surrounding garment textiles. BfR Information No. 018/2007, 1 June 2007
    7. Budavari S (1989) The Merck index. An encyclopedia of chemicals, drugs, and biologicals, 11th edn. Rahway, NJ
    8. Carr SW, Gore B, Anderson MW (1997) 29Si27Al and 1H solid-state NMR study of the surface of zeolite MAP. Chem Mater 9:1927-932 CrossRef
    9. Cefali EA, Nolan JC, McConnell WR, Walters DL (1995) Pharmacokinetic study of zeolite a, sodium aluminosilicate, magnesium silicate, and aluminium hydroxide in dogs. Pharm Res 12:270-74 CrossRef
    10. Cefali EA, Nolan JC, McConnell WR, Walters DL (1996) Bioavailability of silicon and aluminium from zeolite a in dogs. Int J Pharm 127:147-54 CrossRef
    11. CIR (2003) Cosmetic Ingredient Review. Final report on the safety assessment of aluminum silicate, calcium silicate, magnesium aluminum silicate, magnesium silicate, magnesium trisilicate, sodium magnesium silicate, zirconium silicate, attapulgite, bentonite, Fuller’s Earth, hectorite, kaolin, lithium magnesium silicate, lithium magnesium sodium silicate, montmorillonite, pyrophyllite, and zeolite. Int J Toxicol 22 (Suppl 1):37-02
    12. Cook TE, Cilley WA, Savitsky AC, Wiers BH (1982) Zeolite A hydrolysis and degradation. Environ Sci Technol 16:344-50 CrossRef
    13. CSTEE (2003) Opinion of the scientific committee on toxicity, ecotoxicity and the environment (CSTEE) on the environmental impact (reduction in eutrophication) that would result from banning sodium tripolyphosphate (STPP) in household detergents. Adopted by the CSTEE during the 40th plenary meeting of 12-3 November 2003. http://europa.eu.int/comm/health/ph_risk/committees/sct/documents/out202_en.pdf. Cited 06 Feb 2008
    14. EFSA (2004) Opinion of the Scientific Panel on additives and products or substances used in animal feed on the request from the Commission on the use of synthetic sodium aluminium silicate (zeolite) for the reduction of risk of milk fever in dairy cows. The EFSA Journal 160:1-1
    15. EFSA (2007) Scientific opinion of the panel on additives and products or substances used in animal feed on the safety of zeolite as a feed additive for dairy cows. The EFSA Journal 523:1-1
    16. EC (2003) European Commission. Technical guidance documents on risk assessment in support of commission directive 93/67/EEC on risk assesment for new notified substances; commission regulation (EC) no 1488/94 on risk assesment for existing substances; directive 98/8/EC of the European parliament and of the council concerning the placing of biocidal products on the market
    17. Fach E, Waldman WJ, Williams M et al (2002) Analysis of the biological and chemical reactivity of zeolite-based aluminosilicate fibers and particulates. Environ Health Perspect 110:1087-096
    18. FAO/WHO (2006) Summary and conclusions of the sixty-seventh meeting of the Joint FAO/WHO Expert Committee on Food Additives (JECFA), Rome, 20-9 June 2006. JECFA 67/SC. http://www.who.int/ipcs/food/jecfa/summaries/summary67.pdf. Cited 06 Feb 2008
    19. Fubini B, Mollo L (1995) Role of iron in the reactivity of mineral fibers. Toxicol Lett 82/83:951-60 CrossRef
    20. Fubini B, Mollo L, Giamello E (1995) Free radical generation at the solid/liquid interface in iron containing minerals. Free Rad Res 23:593-14 CrossRef
    21. Gloxhuber C, Potokar M, Pittermann W et al (1983) Zeolite A—a phosphate substitute for detergents: toxicological investigation. Food Chem Toxicol 21:209-20 CrossRef
    22. Gudmundsson A, L?ndahl J, Bohgard M (2007) Methodology for identifying particle sources in indoor environments. J Environ Monit 9:831-38 CrossRef
    23. HERA (2004) Human & Environmental Risk Assessment on ingredients of European household cleaning products. Zeolite A (represented by CAS Number 1344-00-9 (Sodium aluminium silicate) and by CAS Number 1318-02-1 (Zeolites). Version 3.0, January 2004, by A.I.S.E. & CEFIC. http://www.heraproject.com/files/8-F-04-%20HERA%20Zeolite%20full%20V3%20web%20wd.pdf. Cited 06 Feb 2008
    24. IARC (1997) International Agency for Research on Cancer. IARC monographs on the evaluation of carcinogenic risks of chemicals to humans vol 68. Silica, some silicates, coal dust and para-aramid fibrils. Lyon, France
    25. IUPAC (1979) International Union of Pure and Applied Chemistry. Definitive chemical nomenclature and formulation of compositions of synthetic and natural zeolites. Pure Appl Chem 51:1091-100
    26. IUPAC (2001) International Union of Pure and Applied Chemistry. Risk Assessment for Occupational Exposure to Chemicals. A review of current methodology (IUPAC technical report). Pure Appl Chem 73: 993-031
    27. Kerr G (1989) Synthetic Zeolites. Scientific American, July 1989: 82-7
    28. Maltoni C, Minardi F (1988) First available results of long-term carcinogenicity bioassay on detergency zeolites (MS 4A and MS 5A). Ann NY Acad Sci 534:978-85 CrossRef
    29. Matthies W, L?hr A, Ippen H (1990) Bedeutung von Rückst?nden von Textilwaschmitteln aus dermatotoxickologischer Sicht. Dermatosen 38:184-89 [in German]
    30. Newsam JM (1986) The zeolite cage structure. Science 231:1093-099 CrossRef
    31. Nolen GA, Dierkman TA (1983) Test for aluminosilicate teratogenicity in rats. Food Chem Toxicol 21:697 CrossRef
    32. NTIS (1973) National Technical Information Service, USA. Compound report: FDA 71-5. Prepared for FDA, US Dept of Commerce, Springfield, VA, PB-223-810
    33. NTIS (1979) National Technical Information Service, USA. Compound report: F76- 001, sodium aluminum silicate. Prepared for FDA, US Dept of Commerce, Springfield, VA, PB89- 193650
    34. OECD (2006) Organisation for Economic Co-operation and Development. SIDS Programme. Documents on the category “crystalline, non-fibrous zeolites- presented at the 23rd SIDS Initial Assessment Meeting (SIAM), October 2006 in Jeju, Korea
    35. Prandi L, Bodoardo S, Penazzi N, Fubini B (2001) Redox state and mobility of iron at the asbestos surface: a voltammetric approach. J Mater Chem 11:1495-501 CrossRef
    36. Prival MJ, Simmon VF, Mortelmans KE (1991) Bacterial mutagenicity testing of 49 food ingredients gives very few positive results. Mutat Res 260:321-29 CrossRef
    37. Prud’homme de Lodder LCH, Bremmer HJ, van Engelen JGM (2006) Cleaning Products Fact Sheet. RIVM report 320104003/2006. http://www.rivm.nl/bibliotheek/rapporten/320104003.pdf. Cited 06 Feb 2008
    38. Rodriguez C, Calvin G, Lally C, Lachapelle JM (1994) Skin effects associated with wearing fabrics washed with commercial laundry detergents. J Cutan Ocular Toxicol 13:39-5 CrossRef
    39. RPA (2006) Risk Policy Analysis. Non-surfactant organic ingredients and zeolite-based detergents. Final report prepared for the European Commission. June 2006
    40. Sainio EL (1996) Detergent residues in textiles. J Consumer Stud Home Econom 20:83-1 CrossRef
    41. Smulders E, R?hse W, von Rybinski W et al (2003) Toxicology. In: Smulders E (ed) Laundry detergents. Wiley, New York
    42. Thilsing-Hansen T, J?rgensen RJ (2001) Hot topic: prevention of parturient paresis and subclinical hypocalcemia in dairy cows by zeolite A administration in the dry period. J Dairy Sci 84:691-93 CrossRef
    43. Van de Plassche EJ et al (1998) Moret Ernst & Young Management Consultants (Second Draft). Rep. No. 601503 013, Nov. 1-4. Cited in: A.I.S.E.-HERA LAS Risk Assessment, July 2002
    44. Wagner JC, Skidmore JW, Hill RJ, Griffiths DM (1985) Erionite exposure and mesotheliomas in rats. Br J Cancer 51:727-30
    45. Weegels MF (1997) Exposure to chemicals in consumer product use. Faculty of Industrial Design Engineering, Delft University of Technology, The Netherlands
    46. Wenninger JA, Canterbery RC, McEwen Jr GN (2000) International cosmetic ingredient dictionary and handbook, 8th edn, vols 1-
    47. Zeiger E, Anderson B, Haworth S et al (1987) Salmonella mutagenicity tests: III. Results from the testing of 255 chemicals. Environ Mutagenesis 9:1-10 CrossRef
  • 作者单位:Claudia Fruijtier-P?lloth (1)

    1. CATS Consultants GmbH, Toxicology and Preclinical Affairs, Saarburgstr. 31, 82166, Gr?felfing, Germany
  • ISSN:1432-0738
文摘
Synthetic zeolites are replacing phosphates as builders in laundry detergents; workers and consumers may, therefore, increasingly be exposed to these materials and it is important to assess their safety. This article puts mechanistic, toxicological and exposure data into context for a safety assessment. Zeolites are hygroscopic compounds with ion-exchanging properties. They may partially decompose under acidic conditions such as in the stomach releasing sodium ions, silicic acid and aluminum salts. The intact molecule is not bioavailable after oral intake or exposure through the dermal and inhalational routes. Under current conditions of manufacture and use, no systemic toxicity is to be expected from neither the intact molecule nor the degradation products; a significant effect on the bioavailability of other compounds is not likely. Zeolites may cause local irritation. It is, therefore, important to minimise occupational exposure. The co-operation of detergent manufacturers with the manufacturers of washing machines is necessary to find the right balance between environmental aspects such as energy and water savings and the occurrence of detergent residues on textiles due to insufficient rinsing.

© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号

地址:北京市海淀区学院路29号 邮编:100083

电话:办公室:(+86 10)66554848;文献借阅、咨询服务、科技查新:66554700