Facile electrochemical growth of nanostructured copper phthalocyanine thin film via simultaneous anodic oxidation of copper and dilithium phthalocyanine for photoelectrochemical hydrogen evolution
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- 作者：R. S. Vishwanath ; Sakthivel Kandaiah
- 关键词：Photoelectrochemical hydrogen evolution ; Electrodeposition ; Photocathodes ; Copper phthalocyanine ; Dilithium phthalocyanine
- 刊名：Journal of Solid State Electrochemistry
- 出版年：2016
- 出版时间：March 2016
- 年：2016
- 卷：20
- 期：3
- 页码：767-773
- 全文大小：1,258 KB
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Sakthivel Kandaiah (1)
1. School of Chemical Sciences, REVA University, Bangalore, Karnataka, 560064, India - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Physical Chemistry
Analytical Chemistry
Industrial Chemistry and Chemical Engineering
Characterization and Evaluation Materials
Condensed Matter
Electronic and Computer Engineering - 出版者：Springer Berlin / Heidelberg
- ISSN：1433-0768
文摘
We present a novel electrochemical approach to grow copper phthalocyanine (CuPc) thin-film photoelectrodes through anodic oxidation of copper and dilithium phthalocyanine (Li2Pc). This circumvents the challenges associated with the electrochemical processing of unsubstituted CuPc from solution. The potentiostatic co-electrooxidation reaction at the heterogeneous interface favors the growth of CuPc thin film. The surface morphology of thin film exhibits nanorod-like features. UV-Vis, grazing angle Fourier transform infrared (FTIR), and grazing angle X-ray diffraction patterns reveal that the nanocrystalline phase corresponds only to α-CuPc and no admixture of other polymorphs. Photocurrent measurement shows a stable photoresponse in neutral medium. The photoelectrochemical hydrogen evolution on p-type CuPc coated copper photocathode shows an enhanced activity over bare copper and indium tin oxide (ITO) electrodeposited with CuPc and monolithium phthalocyanine radical (LiPc) thin films.