Synthesis, Antimicrobial Activity and Colorimetric Studies of Some New Bromo-quinazolinone Derivative as Potential Reactive Dyes

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• 作者：Divyesh R. Patel (1) divyeshpatel905@gmail.com
  Keshav C. Patel (1)
• 关键词：Quinazolinone – ; Solvatochromism – ; Pharmacological screening – ; Colorimetric data – ; Thermogravimetric analysis
• 刊名：Arabian Journal for Science and Engineering
• 出版年：2012
• 出版时间：July 2012
• 年：2012
• 卷：37
• 期：5
• 页码：1347-1368
• 全文大小：1.0 MB
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• 作者单位：1. Department of Chemistry, Veer Narmad South Gujarat University, Surat, 395007 Gujarat, India

文摘

The objective of the current study was to introduce the quinazolinone molecule into a conventional reactive dye system. On this basis ten novel quinazolinone-based monochloro-s-triazine reactive dyes (7a–j) were rapidly and efficiently synthesized by coupling route of diazotized 3-{4′-[4′′-amino-2′′,5′′-dichlorobenzyl]-2′, 5′-dichlorophenyl}-6-bromo-2-phenylquinazolin-4(3H)-one (3) with a variety of m-nitro anilino cyanurated coupling components (6a–j). Their characterization was done using elemental analysis, UV–Vis, IR, 1H NMR and 13C NMR spectroscopy. The solvatochromism was evaluated with respect to spectroscopic properties in organic solvents, viz., DMSO, DMF, methanol, acetic acid and chloroform. A detailed study of pharmacological screening (in vitro), solvatochromic effect, fastness properties, colorimetric data (L*, a*, b*, c*, H*, K/S) and thermogravimetric analysis was also investigated. These dyes showed generally moderate to very good light fastness and good to excellent washing and rubbing fastness properties and also showed good antimicrobial activity.