Synthesis and characterization of a novel ferrocenyl-terminated percec-type dendron and application for redox batteries

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• 作者：Zhiyu Cheng (1)
  Pingru Xu (1)
  Bing Guo (1)
  Yongfu Qiu (1)
  Hongbo Fan (1)
  Xueyi Chang (2)
  Biye Ren (2)
  
  1. College of Chemistry and Environmental Engineering ; Dongguan University of Technology ; Dongguan ; 523808 ; People鈥檚 Republic of China
  2. Research Institute of Materials Science ; South China University of Technology ; Guangzhou ; 510640 ; People鈥檚 Republic of China
  
• 关键词：Percec ; type dendron ; Ferrocene ; Redox ; Battery
• 刊名：Ionics
• 出版年：2015
• 出版时间：May 2015
• 年：2015
• 卷：21
• 期：5
• 页码：1489-1494
• 全文大小：4,223 KB
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• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Electrochemistry
  Materials Science
  Physical Chemistry
  Condensed Matter
  Renewable Energy Sources
  Electrical Power Generation and Transmission
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1862-0760

文摘

A novel ferrocenyl-terminated percec-type dendron 3,4,5-tris (11-ferrocenylundecyloxy) benzoic acid (Fc3CO2H) was synthesized for the first time through nucleophilic substitution reaction between 11-bromoundecyl ferrocene and methyl 3,4,5-trihydroxybenzoate, followed by a hydrolysis process. The structural characteristics of the resultant dendron Fc3CO2H were confirmed through NMR, Fourier transform infrared (FT-IR), and elemental analysis. Furthermore, its stacking structures and physical properties were detected by X-ray diffraction (XRD), thermogravimetry (TG) analysis, differential scanning calorimetry (DSC), and polarized optical microscope (POM). Both cyclic voltammograms (CV) and galvanostatic charge/discharge measurements indicate the as-synthesized dendron has high electrochemical stability and redox reversibility, which makes it a promising candidate for redox batteries.