Facet-dependent Cu₂O nanocrystals in manipulating alignment of liquid crystals and photomechanical behaviors

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• 作者：Qian Wang ; Yang Shang ; Li Yu ; Cheng Zou ; Wenhuan Yao ; Dongyu Zhao…
• 关键词：facet ; dependent ; Cu2O nanocrystals ; alignment ; liquid crystals ; photoactuators
• 刊名：Nano Research
• 出版年：2016
• 出版时间：September 2016
• 年：2016
• 卷：9
• 期：9
• 页码：2581-2589
• 全文大小：1,617 KB
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chinese Library of Science
  Chemistry
  Nanotechnology
  
• 出版者：Tsinghua University Press, co-published with Springer-Verlag GmbH
• ISSN：1998-0000
• 卷排序：9

文摘

Manipulating the alignment of liquid crystals (LCs) is a hot and fundamental issue for their applications in block copolymers, photonics, actuators, biosensors, and liquid-crystal displays. Here, the surface characteristic of Cu₂O nanocrystals was well controlled to manipulate the orientation of the LCs. The mechanism of the orientation of the LCs induced by Cu₂O nanocrystals was elucidated based on the interaction between the LCs and Cu₂O nanocrystals. To comprehensively prove our assumption, different types of LCs (nematic, cholesteric, and smectic) as well as the same type of LCs with different polarities were selected in our system. Moreover, the photomechanical behaviors of the LC polymer composites demonstrated that the alignment of LCs can be effectively manipulated using Cu₂O nanocrystals.