Structural Polymorphism of Mn-Doped BaTiO3
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- 作者：N. T. Dang ; D. P. Kozlenko ; T. L. Phan ; S. E. Kichanov…
- 关键词：Multiferroics ; ferroelectricity ; neutron diffraction ; phase transformation ; barium titanate
- 刊名：Journal of Electronic Materials
- 出版年：2016
- 出版时间：May 2016
- 年：2016
- 卷：45
- 期：5
- 页码：2477-2483
- 全文大小：1,654 KB
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D. P. Kozlenko (2)
T. L. Phan (3)
S. E. Kichanov (2)
N. V. Dang (4)
T. D. Thanh (5)
L. H. Khiem (6)
S. H. Jabarov (7)
T. A. Tran (8)
D. B. Vo (9)
B. N. Savenko (2)
1. Institute of Research and Development, Duy Tan University, Da Nang, 550000, Vietnam
2. Frank Laboratory of Neutron Physics, Joint Institute for Nuclear Research, 141980, Dubna, Russia
3. Department of Physics and Oxide Research Center, Hankuk University of Foreign Studies, Yongin, 449-791, Korea
4. Faculty of Physics, College of Science, Thai Nguyen University, Thai Nguyen, 250000, Vietnam
5. Institute of Materials Science, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Hanoi, 100000, Vietnam
6. Advanced Center for Physics, Institute of Physics, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Hanoi, 100000, Vietnam
7. Institute of Physics, ANAS, 1143, Baku, Azerbaijan
8. Ho Chi Minh City University of Technology and Education, Ho Chi Minh, 700000, Viet Nam
9. Department of Physics, Ho Chi Minh City University of Pedagogy, Ho Chi Minh, 700000, Vietnam - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Optical and Electronic Materials
Characterization and Evaluation Materials
Electronics, Microelectronics and Instrumentation
Solid State Physics and Spectroscopy - 出版者：Springer Boston
- ISSN：1543-186X
文摘
The crystal structure of BaTi1−x Mn x O3 (0 ≤ x ≤ 0.5) has been determined by means of neutron powder diffraction. Upon Mn doping, the BaTi1−x Mn x O3 system undergoes structural transformations from a polar tetragonal structure with space group P4mm to a non-polar 6H-type hexagonal structure with space group P6 3 /mmc at x > 0.01, and then to a non-polar 12R-type rhombohedral structure with space group R-3m at x > 0.12. For the ferroelectric tetragonal phase, Mn doping leads to a reduction of the spontaneous polarization and the Curie temperature. In the 6H structure, Ti atoms display a strong preference for the corner-sharing octahedral sites, whereas both Ti and Mn randomly occupy the octahedral sites in the face-sharing dimers. In the 12R-structure, Ti atoms also have a strong preference for the corner-sharing octahedral sites, whereas Mn atoms occupy the octahedral sites at the centers of the face-sharing octahedral trimers. Both Ti and Mn atoms are distributed over the octahedral sites at the borders of the trimers. The absence of long-range magnetic order in the 6H-type and 12R-type phases was observed, which is due to the presence of the non-magnetic Ti ions at the centers of the corner-sharing octahedra connecting the face-sharing dimers (6H-type) and trimers (12R-type), breaking the magnetic interaction between the dimers/trimers and isolating them from each other.