Donor–Acceptor Dyes for Organic Photovoltaics

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• 关键词：Bulk heterojunctions ; D ; A dyes ; Dipole moment ; Merocyanines ; Organic photovoltaics ; Tandem solar cell
• 刊名：Advances in Polymer Science
• 出版年：2017
• 出版时间：2017
• 年：2017
• 卷：272
• 期：1
• 页码：193-214
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• 作者单位：Alhama Arjona-Esteban (20)
  Martin Robert Lenze (21)
  Klaus Meerholz (21)
  Frank Würthner (20)
  
  20. Institut für Organische Chemie and Center for Nanosystems Chemistry, Universität Würzburg, Am Hubland, 97074, Würzburg, Germany
  21. Department of Chemistry, University of Cologne, Luxemburgerstr. 116, 50939, Cologne, Germany
  
• 丛书名：Elementary Processes in Organic Photovoltaics
• ISBN：978-3-319-28338-8
• 卷排序：272

文摘

Small-molecule π-systems bearing donor (D) and acceptor (A) groups constitute an interesting class of dyes because of their tunable strong absorption, which covers the visible and near-infrared range. The dipolarity associated with D–A structures directs antiparallel stacking arrangements in the solid state, thus reducing the dipolar disorder at the supramolecular level. Their straightforward synthesis and purification make them good candidates for photovoltaic application with power conversion efficiencies >6 %. This review summarizes the application of D–A dyes, and in particular merocyanines, in organic photovoltaics in recent years.