Adsorption of cationic nanospheres on cotton fibers: the effect of emulsifiers used in the cationic emulsion polymerization

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• 作者：Fei Wang (1)
  KuanJun Fang (1)
  
• 关键词：Cationic nanospheres ; Adsorption ; Cotton fibers ; Cationic emulsifier ; Colloidal feature
• 刊名：Colloid & Polymer Science
• 出版年：2014
• 出版时间：September 2014
• 年：2014
• 卷：292
• 期：9
• 页码：2375-2383
• 全文大小：1,623 KB
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• 作者单位：Fei Wang (1)
  KuanJun Fang (1)
  
  1. The Growing Base for State Key Laboratory of Fiber Materials and Modern Textiles, College of Chemical and Environmental Engineering, Qingdao University, 308 Ningxia Road, Qingdao, 266071, China
  
• ISSN：1435-1536

文摘

Cationic p(St-co-BA) nanospheres were prepared and their adsorption on cotton fibers was carried out. The effect of Gemini emulsifier ethanediyl bis(hexadecyl dimethyl ammonium bromide) (G16-2-16) on the colloidal features and adsorption properties of the cationic nanospheres was investigated. To get a clear understanding, the corresponding single-chain emulsifier hexadecyl trimethyl ammonium bromide (CTAB) was used as a comparison. Colloidal features, such as particle size and surface charge density, and adsorption properties, such as adsorption rate, were measured. G16-2-16 produced cationic p(St-co-BA) nanospheres with bigger particle size, better monodispersity, and higher surface charge density than CTAB. Compared with CTAB, G16-2-16 resulted in higher adsorption rate and more uniform arrangement of nanospheres at the cotton fiber surface.